Enantioselective synthesis of eucomols using sharpless catalytic asymmetric dihydroxylation

被引：12

作者：

Jew, SS ^{[1
]}

Kim, HA ^{[1
]}

Kim, JH ^{[1
]}

Park, HG ^{[1
]}

机构：

[1] Seoul Natl Univ, Coll Pharm, Seoul 151742, South Korea

来源：

HETEROCYCLES | 1997年 / 46卷

关键词：

D O I：

10.3987/COM-97-S24

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel synthetic method was developed for eucomols, (S)-3-hydroxyomoisoflavanones. Addition of aryllithium to aldehyde ((S)-9) obtained by asymmetric dihydroxylation of 4, followed by the formation of cyclic ether, gave eucomols, (S)-3-hydroxyhomoisoflavanones (1a-e).

引用

页码：65 / 70

页数：6

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