Enantioselective synthesis of eucomols using sharpless catalytic asymmetric dihydroxylation

被引：12
|
作者：
Jew, SS [1 ]
Kim, HA [1 ]
Kim, JH [1 ]
Park, HG [1 ]
机构：
[1] Seoul Natl Univ, Coll Pharm, Seoul 151742, South Korea
来源：
HETEROCYCLES | 1997年 / 46卷
关键词：
D O I：
10.3987/COM-97-S24
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel synthetic method was developed for eucomols, (S)-3-hydroxyomoisoflavanones. Addition of aryllithium to aldehyde ((S)-9) obtained by asymmetric dihydroxylation of 4, followed by the formation of cyclic ether, gave eucomols, (S)-3-hydroxyhomoisoflavanones (1a-e).
引用
收藏
页码：65 / 70
页数：6
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