Two conformers in solution and solid state for a novel phosphoramidate -: Synthesis, characterization and crystal structures of C6H5C(O)NHP(O)[NH(tert-C4H9)]2 and CCl3C(O)NHP(O)[NH(tert-C4H9)]2

被引：32
|
作者：
Gholivand, K [1 ]
Pourayoubi, M [1 ]
机构：
[1] Tarbiat Modarres Univ, Dept Chem, Tehran, Iran
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 8-9期
关键词：
crystal structure; phosphoric triamide; NMR spectroscopy;
D O I：
10.1002/zaac.200400136
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new phosphoramidates with formula RC(O)NHP(O)[NH(tert-C4H9)](2), R=C6H5, (1) and CCl3, (2) were synthesized and characterized by IR, H-1-, C-13-, P-31 NMR, mass spectroscopy and elemental analysis. The structures confirmed by X-ray single crystal determination. Compound 1 appears as two conformers (1a and 1b) in solid state as well as solution. Both compounds (1 and 2) exist in the polymeric chains in crystalline lattice produced by hydrogen bonding that for compound 1, there are two independent infinite chains; each of them composed of one of the two conformers.
引用
收藏
页码：1330 / 1335
页数：6
相关论文
共 50 条
  • [41] Synthesis and crystal structure of [Mo(C9H6NO)2(O)2] (C9H6NO=8-quinolinol)
    Wang, JP
    Niu, JY
    Zhou, ZY
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2001, 17 (05) : 709 - 712
  • [42] Synthesis and characterization of three novel molybdenum(VI) complexes: Mononuclear [MoO2(C6H4(O)CH=NCH(COO)CH2C=(O)NH2)], [MoO2(C19H19N2O5)(CH3OH)]Cl • CH3OH and dinuclear [Mo2O4(C6H4(O)CH=NCH(COO)CH2C=(O)NH2)2]
    Cindric, Marina
    Galin, Gordana
    Matkovi-Calogovic, Dubravka
    Novak, Predrag
    Hrenar, Tomica
    Ljubic, Ivan
    Novak, Tanja Kajfez
    POLYHEDRON, 2009, 28 (03) : 562 - 568
  • [43] C2H12N6C4O4<middle dot>2H2O and Na2C4O4<middle dot>3H2O: Two Ultraviolet Birefringent Compounds with the [C4O4]2- Group
    Zhang, Xiaodong
    Xu, Bohui
    Xiao, Deshuai
    Dong, Linfeng
    Zhang, Xinyuan
    Gong, Pifu
    Lin, Zheshuai
    INORGANIC CHEMISTRY, 2024, 63 (38) : 17907 - 17913
  • [44] Crystal structure and characterization of [2,5-(CH3O)2C6H3NH3]4P4O12•2H2O
    Aloui, Z
    Abid, S
    Rzaigui, M
    MATERIALS RESEARCH BULLETIN, 2005, 40 (12) : 2056 - 2063
  • [45] Syntheses and Crystal Structures of [Na（H2O）](C17H13O6SO3)·2H2O and [Ni（H2O）6](C17H13O6SO3)2·4H2O
    张尊听
    郭亚宁
    刘谦光
    ChineseJournalofChemistry, 2004, (09) : 971 - 977
  • [46] Macro-, micro-, nano- and crystal structures of a homodinuclear complex [NH3(CH2)3NH3]2{Na2[(C6H4O2)2](C6H4O2H)2}
    Lu Xiao-Ming
    Wei Chun-Xia
    Wang Zhen
    Ye Chao-Hui
    CHINESE JOURNAL OF CHEMISTRY, 2007, 25 (08) : 1126 - 1130
  • [47] Syntheses and crystal structures of [Na(H2O)](C17H13O6SO3)• 2H2O and [Ni(H2O)6](C17H13O6SO3)2•4H2O
    Zhang, ZT
    Guo, YN
    Liu, QG
    CHINESE JOURNAL OF CHEMISTRY, 2004, 22 (09) : 971 - 977
  • [48] Synthesis, crystal structure and fluorescence property of [Eu(C10H9N2O4)(C10H8N2O4)(H2O)3]•0.5bipy•3H2O
    Wu, WT
    He, SY
    Hu, HM
    Wang, YY
    Shi, QZ
    ACTA CHIMICA SINICA, 2005, 63 (22) : 2032 - 2036
  • [49] Synthesis and characterization of N-thiophosphorylated thioureas RC(S)NHP(S)(OiPr)2 (p-(4-imidazol-1-yl)-C6H4NH, p-NC-C6H4NH, (CH2=CH-CH2)2N): Unexpected formation of o-HO-C6H4NHC(S)NHP(S)(OiPr)2 from p-NC-C6H4NHC(S)NHP(S)(OiPr)2
    Safin, Damir A.
    Babashkina, Maria G.
    Bolte, Michael
    Klein, Axel
    POLYHEDRON, 2010, 29 (02) : 715 - 718
  • [50] Hydrothermal Synthesis and Structure of [Mn（C8H5NO4）·H2O]n·2nH2O
    廖秋霞
    姚元根
    Chinese Journal of Structural Chemistry, 2006, (04) : 465 - 468
12345