Two conformers in solution and solid state for a novel phosphoramidate -: Synthesis, characterization and crystal structures of C6H5C(O)NHP(O)[NH(tert-C4H9)]2 and CCl3C(O)NHP(O)[NH(tert-C4H9)]2

被引：32
|
作者：
Gholivand, K [1 ]
Pourayoubi, M [1 ]
机构：
[1] Tarbiat Modarres Univ, Dept Chem, Tehran, Iran
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 8-9期
关键词：
crystal structure; phosphoric triamide; NMR spectroscopy;
D O I：
10.1002/zaac.200400136
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new phosphoramidates with formula RC(O)NHP(O)[NH(tert-C4H9)](2), R=C6H5, (1) and CCl3, (2) were synthesized and characterized by IR, H-1-, C-13-, P-31 NMR, mass spectroscopy and elemental analysis. The structures confirmed by X-ray single crystal determination. Compound 1 appears as two conformers (1a and 1b) in solid state as well as solution. Both compounds (1 and 2) exist in the polymeric chains in crystalline lattice produced by hydrogen bonding that for compound 1, there are two independent infinite chains; each of them composed of one of the two conformers.
引用
收藏
页码：1330 / 1335
页数：6
相关论文
共 50 条
  • [31] Synthesis, crystal structure and luminescent property of [Zn(C12H9O3)2(C10H8N2)n○nH2O
    Li Wei-Qi
    Feng Xia
    Feng Yun-Long
    Wen Yi-Hang
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (06) : 701 - 706
  • [32] Synthesis, Crystal Structure and Luminescent Property of [Zn(C12H9O3)2(C10H8N2)]n·nH2O
    李伟琦
    封霞
    冯云龙
    温一航
    Chinese Journal of Structural Chemistry, 2008, (06) : 701 - 706
  • [33] Synthesis and characterization of a new octamolybdate (NH4)4[Mo8O24(C3H2O2)2] • 4H2O
    Wang, Shoujiang
    Mo, Shaofen
    Liu, Zhen-Gang
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2012, 57 (03) : 430 - 433
  • [34] Synthesis, crystal structure and properties of [Zn2(C9H6N7O)4]•5(H2O)
    Zhu, Yu-Fang
    Xia, Hua
    JOURNAL OF CHEMICAL RESEARCH, 2012, (03) : 169 - 171
  • [35] Synthesis and crystal structure of [Ni(H2O)6][Ni(H2O)2(C4H2O4)]•4H2O
    Zheng, YQ
    Kong, ZP
    JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (11) : 967 - 973
  • [36] Solid and solution state NMR spectra and the structure of the gallium citrate complex (NH4)3[Ga(C6H5O7)2]•4H2O
    Hawkes, GE
    O'Brien, P
    Salacinski, H
    Motevalli, M
    Abrahams, I
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2001, (04) : 1005 - 1011
  • [37] Synthesis and characterization of a new cyclohexaphosphate, (C10H13NH3)4(H3O)2(P6O18)•3(H2O)
    Amri, O.
    Abid, S.
    Rzaigui, M.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2008, 183 (08) : 1984 - 1993
  • [38] Synthesis and structural characterization of Pd[CH3O(O)C6H3CHNNC(S)NH2](C5H5N)
    Zi, FL
    Zhou, YZ
    Lu, XM
    Liu, SC
    Jin, XL
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (02) : 200 - 202
  • [39] Crystal structure and bioactivity of complex [Gd(C10H9N2O4)(C10H8N2O4)(H2O)3]2•phen•4H2O
    He, SY
    Yang, R
    Wu, WT
    Shi, QZ
    Wang, DQ
    An, DR
    CHINESE JOURNAL OF CHEMISTRY, 2005, 23 (09) : 1198 - 1202
  • [40] Synthesis and Structural Characterization of Pd[CH3O（O）C6H3CHNNC（S）NH2]（C5H5N）
    ZI Feng-Lan ZHOU Yin-Zhuang② LU Xiao-Ming LIU Shun-Cheng (Department of Chemistry
    结构化学, 2003, (02) : 200 - 202
12345