Bicomponent aligned nanofibers of N-carboxyethylchitosan and poly(vinyl alcohol)

被引：39

作者：

Mincheva, Rosica ^{[1
]}

Manolova, Nevena ^{[1
]}

Rashkov, Iliya ^{[1
]}

机构：

[1] Bulgarian Acad Sci, Inst Polymers, Lab Bioact Polymers, BU-1113 Sofia, Bulgaria

来源：

EUROPEAN POLYMER JOURNAL | 2007年 / 43卷 / 07期

关键词：

electrospinning; water-resistant nanofibers; thermal crosslinking; n-carboxyethylchitosan; poly(vinyl alcohol); aligned nanofibers;

D O I：

10.1016/j.eurpolymj.2007.04.020

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Bicomponent nanofibers of N-carboxyethylchitosan (CECh) and poly(vinyl alcohol) (PVA) were obtained by electrospinning of mixed aqueous solutions. The electrospinning of CECh-containing nanofibers was enabled by the ability of PVA to form an elastically deformable entanglement network based on hydrogen bonds. The average diameters of the bicomponent fibers were in the range 100-420 nm. Water-resistant nanofibrous mats were obtained by thermal crosslinking at 100 degrees C for 10 h. Nanofibrous materials with 1D-, 1D-transversery or 3D fiber alignment were obtained depending on the type of the collector used. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2809 / 2818

页数：10

共 29 条

[1]

[Anonymous], 2004, MICROSC MICROANAL

[2] Evaluation of an in situ forming hydrogel wound dressing based on oxidized alginate and gelatin [J].

Balakrishnan, B ;

Mohanty, M ;

Umashankar, PR ;

Jayakrishnan, A .

BIOMATERIALS, 2005, 26 (32) :6335-6342

[3] Structure and interactions in chitosan hydrogels formed by complexation or aggregation for biomedical applications [J].

Berger, J ;

Reist, M ;

Mayer, JM ;

Felt, O ;

Gurny, R .

EUROPEAN JOURNAL OF PHARMACEUTICS AND BIOPHARMACEUTICS, 2004, 57 (01) :35-52

[4] Ultrafine hydrogel fibers with dual temperature- and pH-responsive swelling behaviors [J].

Chen, H ;

Hsieh, YL .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (24) :6331-6339

[5] Electrospun nanofibers: Internal structure and intrinsic orientation [J].

Dersch, R ;

Liu, TQ ;

Schaper, AK ;

Greiner, A ;

Wendorff, JH .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (04) :545-553

[6] Preparation and characterization of a nanoscale poly(vinyl alcohol) fiber aggregate produced by an electrospinning method [J].

Ding, B ;

Kim, HY ;

Lee, SC ;

Shao, CL ;

Lee, DR ;

Park, SJ ;

Kwag, GB ;

Choi, KJ .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2002, 40 (13) :1261-1268

[7] Electrospinning of chitosan solutions in acetic acid with poly(ethylene oxide) [J].

Duan, B ;

Dong, CH ;

Yuan, XY ;

Yao, KD .

JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION, 2004, 15 (06) :797-811

[8] Fabrication of aligned and molecularly oriented electrospun polyacrylonitrile nanofibers and the mechanical behavior of their twisted yams [J].

Fennessey, SF ;

Farris, RJ .

POLYMER, 2004, 45 (12) :4217-4225

[9] A review on polymer nanofibers by electrospinning and their applications in nanocomposites [J].

Huang, ZM ;

Zhang, YZ ;

Kotaki, M ;

Ramakrishna, S .

COMPOSITES SCIENCE AND TECHNOLOGY, 2003, 63 (15) :2223-2253

[10] Electrospun nano-fibre mats with antibacterial properties from quaternised chitosan and poly(vinyl alcohol) [J].

Ignatova, Milena ;

Starbova, Kirilka ;

Markova, Nadya ;

Manolova, Nevena ;

Rashkov, Iliya .

CARBOHYDRATE RESEARCH, 2006, 341 (12) :2098-2107

← 1 2 3 →