Mesoporous molecular sieves as supports for metathesis catalysts

被引：0

作者：

Balcar, Hynek ^{[1
]}

Cejka, Jiri ^{[1
]}

机构：

[1] Acad Sci Czech Republic, J Heyrovsky Inst Phys Chem, Dolejskova 3, Prague 18223 8, Czech Republic

来源：

METATHESIS CHEMISTRY: FROM NANOSTRUCTURE DESIGN TO SYNTHESIS OF ADVANCED MATERIALS | 2007年 / 243卷

关键词：

mesoporous molecular sieves; heterogeneous catalysts; olefin matathesis; matathesis polymerization;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mesoporous molecular sieves represent a new family of inorganic oxides with regular nanostructure, large surface areas, large void volumes, and narrow pore size distribution of mesopores. These materials offer new possibilities for designing highly active and selective catalysts for olefin metathesis and metathesis polymerization. Siliceous sieves MCM-41, MCM-48, SBA-15, and organized mesoporous alumina (OMA) were used as supports for preparation of new molybdenum and rhenium oxide catalysts, as well as for heterogenization of well-defined homogeneous catalysts.

引用

页码：151 / +

页数：3

共 38 条

[1]

Abbenhuis HCL, 1999, ANGEW CHEM INT EDIT, V38, P1058, DOI 10.1002/(SICI)1521-3773(19990419)38:8<1058::AID-ANIE1058>3.0.CO

[2]

2-8

[3] Metathesis of 1-hexene over rhenium oxide supported on ordered mesoporous aluminas:: comparison with Re2O7/γ-Al2O3 [J].

Aguado, J ;

Escola, JM ;

Castro, MC ;

Paredes, B .

APPLIED CATALYSIS A-GENERAL, 2005, 284 (1-2) :47-57

[4]

Balcar H, 2005, STUD SURF SCI CATAL, V156, P795

[5] Rhenium oxide supported on mesoporous organized alumina as a catalyst for metathesis of 1-alkenes [J].

Balcar, H ;

Hamtil, R ;

Zilková, N ;

Cejka, J .

CATALYSIS LETTERS, 2004, 97 (1-2) :25-29

[6] [Rh(cod)Cl]2 complex immobilized on mesoporous molecular sieves MCM-41-a new hybrid catalyst for polymerization of phenylacetylene [J].

Balcar, H ;

Cejka, J ;

Sedlácek, J ;

Svoboda, J ;

Zedník, J ;

Bastl, Z ;

Bosácek, V ;

Vohlídal, J .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 203 (1-2) :287-298

[7] MCM-41 anchored Schrock catalyst Mo(=CHCMe2Ph)(=N-2,6-i-Pr2C6H3)[OCMe(CF3)2]2-activity in 1-heptene metathesis and cross-metathesis reactions [J].

Balcar, H ;

Zilková, N ;

Sedlácek, J ;

Zedník, J .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 232 (1-2) :53-58

[8]

BALCAR H, UNPUB

[9] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[10] Recent advances in the synthesis of supported metathesis catalysts [J].

Buchmeiser, MR .

NEW JOURNAL OF CHEMISTRY, 2004, 28 (05) :549-557

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