A 7Li NMR study of a hard carbon as a function of temperature and lithiation state

被引:0
|
作者
Guerin, K
Fevrier-Bouvier, A
Flandrois, S
Menetrier, M
Simon, B
Biensan, P
机构
[1] CNRS, Ctr Rech Paul Pascal, F-33600 Pessac, France
[2] CNRS, ICMCB, F-33600 Pessac, France
[3] SAFT Rech, F-33074 Bordeaux, France
关键词
Li-7; NMR; lithium-ion batteries; hard carbons;
D O I
10.1080/10587250008025510
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Negative electrodes of lithium-ion batteries containing a hard carbon with different levels of lithiation were characterized by Li-7 NMR experiments. A dramatic effect of washing the lithiated electrodes with the solvent was observed. The spectra of unwashed electrodes in different states of lithiation show that three species seem to be present: covalently bonded, intercalated and pseudo-metallic lithium species, respectively.
引用
收藏
页码:467 / 472
页数:6
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