Boratabenzene rare-earth metal complexes

被引：18
作者：
Cui, Peng [1 ]
Chen, Yaofeng [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
来源：
COORDINATION CHEMISTRY REVIEWS | 2016年 / 314卷
基金：
中国国家自然科学基金;
关键词：
Rare-earth metals; Boron; Heterocycles; Complex; HIGHLY REACTIVE ORGANOLANTHANIDES; X-RAY STRUCTURES; N SIGMA-BOND; POLYMERIZATION CATALYSTS; OLEFIN POLYMERIZATION; STRUCTURAL-CHARACTERIZATION; BORABENZENE DERIVATIVES; LIGANDS; CHEMISTRY; HYDRIDE;
D O I：
10.1016/j.ccr.2015.07.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Boratabenzenes are heterocyclic 6 pi-electron aromatic anions that can serve as surrogates of cyclopentadienyl-type ligands in the rare-earth metal chemistry. The synthesis of mono-, bis- and tris(boratabenzene) rare-earth metal complexes, including the divalent and trivalent rare-earth metal derivatives, their halides, amides, and alkyls are summarized in this review. Their structural features, stoichiometric reactivity, and catalytic activity are also presented. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：2 / 13
页数：12
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