Synthesis and Molecular Structure of a Dimeric Organometallic Indiumsubfluoride

被引：0

作者：

Uhl, Werner ^{[1
]}

Lawerenz, Andreas ^{[1
]}

Layh, Marcus ^{[1
]}

机构：

[1] Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 14期

关键词：

Indium; Metal-metal bonds; Fluorine; Subhalides; Cluster compounds; GA-GA; SINGLE BONDS; IN-IN; CRYSTAL-STRUCTURE; AL-AL; COMPOUND; INDIUM; GALLIUM; SUBHALIDES; FLUORIDES;

D O I：

10.1002/zaac.201400350

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the tetraindium(I) cluster compound In-4[C(SiMe3)(3)](4) (1) with silver tetrafluoridoborate afforded the unique organometallic indium(II) subfluoride [(Me3Si)(3)C(F)In-In(F)C(SiMe3)(3)](2) 2 via selective oxidation of the indium atoms by Ag+. Compound 2 features an In4F4 cage at its molecular core in which two In-In single bonds that are perpendicular to each other are bridged by four fluorine atoms.

引用

页码：2830 / 2833

页数：4

共 50 条

[21] Synthesis, crystal structure and magnetic behaviour of dimeric and polymeric gadolinium trifluoroacetate complexes
John, Daniela
Rohde, Alexander
Urland, Werner
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2006, 61 (06): : 699 - 707
[22] Synthesis and Magnetism of a Dimeric Complex
Lu, Lu
Wang, Jun
Wu, Xi-Ren
Xie, Bin
Wu, Yu
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (11) : 1675 - 1679
[23] Synthesis and Solid-State Structure of Cyclobutyltellurium(IV)-Containing Dimeric Tungstoarsenates(III)
Kandasamy, Balamurugan
Bassil, Bassem S.
Beckmann, Jens
Chen, Banghao
Dalal, Naresh S.
Kortz, Ulrich
JOURNAL OF CLUSTER SCIENCE, 2017, 28 (02) : 825 - 837
[24] Synthesis, Crystal Structure, Fluorescence, and Thermal Properties of a Novel Copper(II) Dimeric Complex
Gao, Yongchao
Xie, Xiaoya
Lu, Huijie
Li, Gang
Zhang, Haifang
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (06) : 425 - 429
[25] Synthesis and molecular structure of phenyl and tolylgermatranes
Lukevics, E
Ignatovich, L
Belyakov, S
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 588 (02) : 222 - 230
[26] Synthesis and molecular structure of a tripodal triaminostibine
Gade, LH
Findeis, B
Gevert, O
Werner, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (05): : 1030 - 1032
[27] Euglena gracilis ascorbate peroxidase forms an intramolecular dimeric structure: its unique molecular characterization
Ishikawa, Takahiro
Tajima, Naoko
Nishikawa, Hitoshi
Gao, Yongshun
Rapolu, Madhusudhan
Shibata, Hitoshi
Sawa, Yoshihiro
Shigeoka, Shigeru
BIOCHEMICAL JOURNAL, 2010, 426 : 125 - 134
[28] Synthesis of organometallic pentalenide complexes
Boyt, Stuart M.
Jenek, Niko A.
Hintermair, Ulrich
DALTON TRANSACTIONS, 2019, 48 (16) : 5107 - 5124
[29] Synthesis and Electrochemistry of Organometallic Cobaltadithiaazulenes
Nomura, Mitsushiro
Imamura, Fumiaki
Nguyen Ba Tuyet Nga
Fujita-Takayama, Chikako
Sugiyama, Toru
Kajitani, Masatsugu
INORGANIC CHEMISTRY, 2012, 51 (20) : 10695 - 10703
[30] A Tetradecanuclear Organometallic Copper(I)-Alkynide Cluster: Synthesis, Crystal Structure, and Luminescent Property
Zhuo, Hong-Yan
Hu, An-Yi
Feng, Lei
Liu, Qing-Yun
Wang, Xing-Po
Sun, Di
JOURNAL OF CLUSTER SCIENCE, 2018, 29 (06) : 1017 - 1022

← 1 2 3 4 5 →