Simple Geometrical Interpretation of the Linear Character for the Zeno-Line and the Rectilinear Diameter

被引：47

作者：

Kulinskii, V. L. ^{[1
]}

机构：

[1] Odessa Natl Univ, Dept Theoret Phys, UA-65026 Odessa, Ukraine

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2010年 / 114卷 / 08期

关键词：

COEXISTENCE-CURVE DIAMETER; STATE; EQUATION; FLUIDS; BEHAVIOR; METALS; MODEL; GAS;

D O I：

10.1021/jp911897k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The unified geometrical interpretation of the linear character of the Zeno-line (unit compressibility line Z = 1) and the rectilinear diameter is proposed. We show that recent findings about the properties of the Zeno-line and striking correlation with the rectilinear diameter line as well as other empirical relations can be naturally considered as the consequences of the projective isomorphism between the real molecular fluids and the lattice gas (Ising) model.

引用

页码：2852 / 2855

页数：4

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