Temperature-Dependent Phase Stable Hybrid Halide Perovskite Films by Chemical Vapor Deposition

被引：6

作者：

Burns, Randy ^{[1
]}

Ngqoloda, Siphelo ^{[2
]}

Klue, Stephen C. ^{[1
]}

Karapetrova, Evguenia ^{[3
]}

Arendse, Christopher J. ^{[1
,2
]}

Guha, Suchismita ^{[1
,2
]}

机构：

[1] Univ Missouri, Dept Phys & Astron, Columbia, MO 65211 USA

[2] Univ Western Cape, Dept Phys & Astron, ZA-7535 Bellville, South Africa

[3] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA

来源：

ACS APPLIED ELECTRONIC MATERIALS | 2022年 / 4卷 / 09期

基金：

美国国家科学基金会; 新加坡国家研究基金会;

关键词：

halide perovskite; X-ray diffraction; chemical vapor deposition; electrical transport; thermal stability; SOLAR-CELLS; ROOM-TEMPERATURE; CRYSTAL; TRANSITIONS; DISORDER;

D O I：

10.1021/acsaelm.2c00449

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Methylammonium lead iodide (MAPbI3-xClx) thin films were synthesized using chemical vapor deposition. Temperature-dependent grazing incidence synchrotron-based X-ray diffraction measurements confirm that the structure of MAP-bI(3-x)Cl(x), where Cl acts more like a dopant, remains throughout in the tetragonal phase in the temperature range of 20-300 K. These studies are further correlated with temperature-dependent photo-luminescence (PL) studies. The PL peak energy monotonically increases with temperature, suggestive of a single-phase behavior. Resistance measurements conducted as a function of temperature show an absence of inflection points, suggesting uniformity in its phase. Between 200 and 325 K, the resistance remains a constant.

引用

页码：4258 / 4264

页数：7

共 35 条

[1] Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].

Baikie, Tom ;

Fang, Yanan ;

Kadro, Jeannette M. ;

Schreyer, Martin ;

Wei, Fengxia ;

Mhaisalkar, Subodh G. ;

Graetzel, Michael ;

White, Tim J. .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641

[2] Direct Observation of Dynamic Symmetry Breaking above Room Temperature in Methylammonium Lead Iodide Perovskite [J].

Beecheri, Alexander N. ;

Semonin, Octavi E. ;

Skelton, Jonathan M. ;

Frost, Jarvist M. ;

Terban, Maxwell W. ;

Zhai, Haowei ;

Alatas, Ahmet ;

Owen, Jonathan S. ;

Walsh, Aron ;

Billinge, Simon J. L. .

ACS ENERGY LETTERS, 2016, 1 (04) :880-887

[3] Organometal halide perovskite solar cells: degradation and stability [J].

Berhe, Taame Abraha ;

Su, Wei-Nien ;

Chen, Ching-Hsiang ;

Pan, Chun-Jern ;

Cheng, Ju-Hsiang ;

Chen, Hung-Ming ;

Tsai, Meng-Che ;

Chen, Liang-Yih ;

Dubale, Amare Aregahegn ;

Hwang, Bing-Joe .

ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (02) :323-356

[4] Entropy-driven stabilization of the cubic phase of MaPbI3 at room temperature [J].

Bonadio, A. ;

Escanhoela, C. A., Jr. ;

Sabino, F. P. ;

Sombrio, G. ;

de Paula, V. G. ;

Ferreira, F. F. ;

Janotti, A. ;

Dalpian, G. M. ;

Souza, J. A. .

JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (02) :1089-1099

[5] Lattice dynamics and vibrational spectra of the orthorhombic, tetragonal, and cubic phases of methylammonium lead iodide [J].

Brivio, Federico ;

Frost, Jarvist M. ;

Skelton, Jonathan M. ;

Jackson, Adam J. ;

Weber, Oliver J. ;

Weller, Mark T. ;

Goni, Alejandro R. ;

Leguy, Aurelien M. A. ;

Barnes, Piers R. F. ;

Walsh, Aron .

PHYSICAL REVIEW B, 2015, 92 (14)

[6] Probing structure-property relationship in chemical vapor deposited hybrid perovskites by pressure and temperature [J].

Burns, Randy ;

Ngqoloda, Siphelo ;

Arendse, Christopher J. ;

Lavina, Barbara ;

Dahal, Ashutosh ;

Singh, Deepak K. ;

Guha, Suchismita .

JOURNAL OF MATERIALS RESEARCH, 2021, 36 (09) :1805-1812

[7] Metal-semiconductor transition in thin film MAPbI3 perovskite [J].

Campanari, Valerio ;

Lucci, Massimiliano ;

Castriotta, Luigi Angelo ;

Paci, Barbara ;

Generosi, Amanda ;

Guaragno, Marco ;

Francini, Roberto ;

Cirillo, Matteo ;

Di Carlo, Aldo .

APPLIED PHYSICS LETTERS, 2020, 117 (26)

[8] Elastic anomalies accompanying phase transitions in (Ca,Sr)TiO3 perovskites:: Part I.: Landau theory and a calibration for STiO3 [J].

Carpenter, Michael A. .

AMERICAN MINERALOGIST, 2007, 92 (2-3) :309-327

[9] Molecular disorder and translation/rotation coupling in the plastic crystal phase of hybrid perovskites [J].

Even, J. ;

Carignano, M. ;

Katan, C. .

NANOSCALE, 2016, 8 (12) :6222-6236

[10] Elucidating the role of chlorine in perovskite solar cells [J].

Fan, Lin ;

Ding, Yi ;

Luo, Jingshan ;

Shi, Biao ;

Yao, Xin ;

Wei, Changchun ;

Zhang, Dekun ;

Wang, Guangcai ;

Sheng, Yun ;

Chen, Yifeng ;

Hagfeldt, Anders ;

Zhao, Ying ;

Zhang, Xiaodan .

JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (16) :7423-7432

← 1 2 3 4 →