C-H carboxylation of heteroarenes with ambient CO2

被引：80

作者：

Fenner, Sabine ^{[1
]}

Ackermann, Lutz ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, Tammannstr 2, D-37077 Gottingen, Germany

来源：

GREEN CHEMISTRY | 2016年 / 18卷 / 13期

关键词：

CATALYZED DIRECT CARBOXYLATION; CARBON-DIOXIDE; BOND; METHYLATION; FIXATION; DFT; FUNCTIONALIZATION; TRANSFORMATIONS; ACTIVATION; ALKYNES;

D O I：

10.1039/c6gc00200e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-H carboxylation of heteroarenes was achieved under transition metal-free reaction conditions with naturally abundant CO2 as the C1 source at relatively low temperature. The C-H carboxylation was mediated by KOt-Bu at atmospheric pressure of CO2, and thereby provided atom- and step-economical access to various heteroaromatic carboxylic acid derivatives.

引用

页码：3804 / 3807

页数：4

共 50 条

[21] Catalytic C(sp)-H carboxylation with CO2 [J].

Zhang, Lin ;

Gao, En-Qing .

COORDINATION CHEMISTRY REVIEWS, 2023, 486

[22] Carboxylation of Benzylic and Aliphatic C-H Bonds with CO2 Induced by Light/Ketone/Nickel [J].

Ishida, Naoki ;

Masuda, Yusuke ;

Imamura, Yuuya ;

Yamazaki, Katsushi ;

Murakami, Masahiro .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (50) :19611-19615

[23] C-H Bond Silylation of Heteroarenes [J].

Khatua, Hillol ;

Das, Subrata ;

Patra, Sima ;

Chattopadhyay, Buddhadeb .

SYNTHESIS-STUTTGART, 2023, 55 (21) :3434-3453

[24] Cobalt-Catalyzed Allylic C(sp3)-H Carboxylation with CO2 [J].

Michigami, Kenichi ;

Mita, Tsuyoshi ;

Sato, Yoshihiro .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (17) :6094-6097

[25] Copper-Catalyzed C-H Carbamoyloxylation of Aryl Carboxamides with CO2 and Amines at Ambient Conditions [J].

Luo, Xiang ;

Song, Xianheng ;

Xiong, Wenfang ;

Li, Jianheng ;

Li, Mingkang ;

Zhu, Zefeng ;

Wei, Shuxian ;

Chan, Albert S. C. ;

Zou, Yong .

ORGANIC LETTERS, 2019, 21 (07) :2013-2018

[26] Direct C-H carboxylation with complexes of the coinage metals [J].

Boogaerts, Ine I. F. ;

Nolan, Steven P. .

CHEMICAL COMMUNICATIONS, 2011, 47 (11) :3021-3024

[27] Pd(II)-catalyzed carboxylation of aromatic C?H bonds with CO2 [J].

Kemper, Gregor ;

Hoelscher, Markus ;

Leitner, Walter .

SCIENCE ADVANCES, 2023, 9 (05)

[28] Rhodium(I)-Catalyzed Direct Carboxylation of Arenes with CO2 via Chelation-Assisted C-H Bond Activation [J].

Mizuno, Hajime ;

Takaya, Jun ;

Iwasawa, Nobuharu .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (05) :1251-1253

[29] Ligand-enabled site-selectivity in a versatile rhodium(II)-catalysed aryl C-H carboxylation with CO2 [J].

Fu, Lei ;

Li, Shangda ;

Cai, Zhihua ;

Ding, Yongzheng ;

Guo, Xiao-Qing ;

Zhou, Li-Peng ;

Yuan, Daqiang ;

Sun, Qing-Fu ;

Li, Gang .

NATURE CATALYSIS, 2018, 1 (06) :469-478

[30] Construction of unsymmetrical heterobiaryls via the Cp*Rh(iii)-catalysed C-H/C-H coupling of heteroarenes [J].

Parmar, Diksha ;

Sharma, Tamanna ;

Sharma, Akhilesh K. K. ;

Sharma, Upendra .

CHEMICAL COMMUNICATIONS, 2023, 59 (63) :9646-9649

← 1 2 3 4 5 →