Heterogeneity explains features of "anomalous" thermodynamics and statistics

被引:42
作者
Gheorghiu, S [1 ]
Coppens, MO [1 ]
机构
[1] Delft Univ Technol, Fac Sci Appl, DelftChemTech, NL-2628 BL Delft, Netherlands
关键词
power-law statistics; polydispersity; student distribution;
D O I
10.1073/pnas.0407191101
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Phenomena characterized by power-law probability distributions abound in nature and the applied sciences. We show that many of these power laws are well described by the Student, or t, distribution, and we discuss the origin of this universality based on three examples (Brownian motion, Knudsen diffusion in rough pores, and bubbly multiphase flow). These case studies are representative for a large class of systems with heterogeneous features, examples of which can be found from Earth sciences to astrophysics, and even in the social sciences. We show that common forms of polydispersity, such as polydispersity arising naturally as a result of aggregation-fragmentation phenomena, typically lie at the basis of the observed scaling. We conclude that complicated arguments based on long-range correlations or nonergodicity are often incorrect or misleading in explaining many naturally observed power laws and, in particular, those described by the Student distribution.
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页码:15852 / 15856
页数:5
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