Characterization of a mixed salt of 1-hydroxypyridin-2-one Pu(IV) complexes

被引：30
作者：
Gorden, Anne E. V.
Xu, Jide
Szigethy, Geza
Oliver, Allen
Shuh, David K.
Raymond, Kenneth N. [1 ]
机构：
[1] LBNL, Glenn T Seaborg Ctr, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 21期
关键词：
D O I：
10.1021/ja070168l
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A single-crystal X-ray diffraction analysis of the mixed salt of hydroxypyridonate Pu(IV) complexes is presented; [Pu(1,2-HOPO)(3)(H2O)(2)center dot ClO4] [Pu(1,2-HOPO)(4)] crystallizes in P2(1) with the asymmetric unit containing two distinct eight-coordinate Pu(IV) complexes, one tris(bidentate) and the other tetrakis(bidentate). The structure of this complex is compared to the analogous Ce(IV)- and Th(IV)-1,2-HOPO structures.
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页码：6674 / +
页数：3
相关论文
共 15 条
[1]   The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].
Allen, FH .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388
[2]   Sequestered plutonium:: [PuIV-5LIO(Me-3,2-HOPO)}2] -: The first structurally characterized plutonium hydroxypyridonate complex (vol 11, pg 2842, 2005) [J].
Gorden, A. E. V. ;
Shuh, D. K. ;
Tiedemann, B. E. F. ;
Wilson, R. E. ;
Xu, J. ;
Raymond, K. N. .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (02) :378-378
[3]   Rational design of sequestering agents for plutonium and other actinides [J].
Gorden, AEV ;
Xu, JD ;
Raymond, KN ;
Durbin, P .
CHEMICAL REVIEWS, 2003, 103 (11) :4207-4282
[4]   Sequestered plutonium:: [PuIV{5LIO(Me-3,2-HOPO)}2] -: The first structurally characterized plutonium hydroxypyridonate complex [J].
Gorden, AEV ;
Shuh, DK ;
Tiedemann, BEF ;
Wilson, RE ;
Xu, JD ;
Raymond, KN .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (09) :2842-2848
[5]   π-π-Stacking and nitro-π-stacking interactions of 1-(4-nitrophenyl)-4-phenyl-2,4-bis(phenylethynyl)butadiene [J].
Kaafarani, BR ;
Wex, B ;
Oliver, AG ;
Bauer, JAK ;
Neckers, DC .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2003, 59 :O227-O229
[6]   Incorporation of hydroxypyridinone ligands into self-assembled monolayers on mesoporous supports for selective actinide sequestration [J].
Lin, YH ;
Fiskum, SK ;
Yantasee, W ;
Wu, H ;
Mattigod, SV ;
Vorpagel, E ;
Fryxell, GE ;
Raymond, KN ;
Xu, JD .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (05) :1332-1337
[7]   SPECIFIC SEQUESTERING AGENTS FOR THE ACTINIDES .9. SYNTHESIS OF METAL-COMPLEXES OF 1-HYDROXY-2-PYRIDINONE AND THE CRYSTAL-STRUCTURE OF TETRAKIS(1-OXY-2-PYRIDONATO)AQUOTHORIUM(IV) DIHYDRATE [J].
RILEY, PE ;
ABUDARI, K ;
RAYMOND, KN .
INORGANIC CHEMISTRY, 1983, 22 (26) :3940-3944
[8]   FERRIC ION SEQUESTERING AGENTS .13. SYNTHESIS, STRUCTURES, AND THERMODYNAMICS OF COMPLEXATION OF COBALT(III) AND IRON(III) TRIS COMPLEXES OF SEVERAL CHELATING HYDROXYPYRIDINONES [J].
SCARROW, RC ;
RILEY, PE ;
ABUDARI, K ;
WHITE, DL ;
RAYMOND, KN .
INORGANIC CHEMISTRY, 1985, 24 (06) :954-967
[9]   Preparation and precise structural determination of a second Ga84 cluster compound.: A first hint for cluster doping and its fundamental consequences in the field of chemistry and physics of nanoscaled metalloid cluster material [J].
Schnepf, A ;
Jee, B ;
Schnöckel, H ;
Weckert, E ;
Meents, A ;
Lubbert, D ;
Herrling, E ;
Pilawa, B .
INORGANIC CHEMISTRY, 2003, 42 (24) :7731-7733
[10]  
SHELDRICK GM, 1996, COMMUNICATION
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