catena-Poly[[[aqua(2,2′-bipyridine-N,N′)nickel(II)]-μ-3,5-dinitrosalicylato-κ3O,O′:O"] 0.2-hydrate]

被引:1
作者
Song, Wen-Dong [1 ]
Guo, Xian-Xia
He, Hong
机构
[1] Guang Dong Ocean Univ, Coll Sci, Zhan Jiang 524088, Peoples R China
[2] Guang Dong Ocean Univ, Sch Agr, Zhan Jiang 524088, Peoples R China
关键词
D O I
10.1107/S1600536807003121
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, {[Ni(C7H2N2O7)(C10H8N2)(H2O)] center dot 0.2H(2)O}(n), the Ni-II atom is coordinated by three O atoms from two symmetry-related 3,5-dinitrosalicylate ligands, two N atoms from one 2,2'-bipyridine and one water molecule, and its environment displays a distorted octahedral geometry. The short face-to-face distances between parallel 2,2'-bipyridine planes of neighbouring complexes and neighbouring one-dimensional chains indicate pi-pi stacking. The packing is further influenced by inter- and intramolecular hydrogen-bond interactions.
引用
收藏
页码:M610 / M612
页数:3
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