Magnetic anisotropy in spherical Fe16N2 core-shell nanoparticles determined by torque measurements

被引:7
作者
Kita, Eiji [1 ,2 ]
Shibata, Kenichi [1 ]
Sasaki, Yuji [3 ]
Kishimoto, Mikio [1 ]
Yanagihara, Hideto [1 ]
机构
[1] Univ Tsukuba, Inst Appl Phys, Tsukuba, Ibaraki 3058573, Japan
[2] Ibaragi Coll, Natl Inst Technol, Hitachinaka, Ibaraki 3128508, Japan
[3] Hitachi Maxell Ltd, 1 Koizumi, Kyoto 6158525, Japan
关键词
ROTATIONAL HYSTERESIS;
D O I
10.1063/1.4974276
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The magnetic anisotropy energy for core-shell alpha"-Fe16N2 nanoparticles was evaluated by the rotational hysteresis loss obtained from magnetic torque measurements. The saturation magnetization of the alpha"-Fe16N2 core was deduced from volume fractions of alpha"-Fe16N2 determined by an analysis of a low-temperature Mossbauer spectrum. The saturation magnetization and the anisotropy energy were found to be 234 emu/cc and 6.9 Merg/cm(3), respectively. These values coincide with those of bulk-like single-phase alpha"-Fe16N2 particles. This crystalline anisotropy is still smaller than the shape anisotropy of the thin films (2 pi Ms-2 = 20 Merg/cm(3)), and a perpendicular magnetic state is not expected for the thin-film form. (C) 2017 Author(s).
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页数:5
相关论文
共 18 条
[1]  
[Anonymous], 1971, M SSBAUER SPECTROSCO, DOI DOI 10.1007/978-94-009-5697-1
[2]   Phase Concentration Determination of Fe16N2 Using State of the Art Neutron Scattering Techniques [J].
Bennett, S. P. ;
Feygenson, M. ;
Jiang, Y. ;
Zande, B. J. ;
Zhang, X. ;
Sankar, S. G. ;
Wang, J. P. ;
Lauter, V. .
JOM, 2016, 68 (06) :1572-1576
[3]   Iron Nitride Family at Reduced Dimensions: A Review of Their Synthesis Protocols and Structural and Magnetic Properties [J].
Bhattacharyya, Sayan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (04) :1601-1622
[4]   Rotational hysteresis in particles for magnetic recording with different switching modes [J].
Bottoni, G .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1996, 155 (1-3) :16-18
[5]   Hard Magnetic Materials: A Perspective [J].
Coey, J. M. D. .
IEEE TRANSACTIONS ON MAGNETICS, 2011, 47 (12) :4671-4681
[6]   Magnetic nitrides [J].
Coey, JMD ;
Smith, PAI .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 200 (1-3) :405-424
[7]   NEW MAGNETIC MATERIAL HAVING ULTRAHIGH MAGNETIC-MOMENT [J].
KIM, TK ;
TAKAHASHI, M .
APPLIED PHYSICS LETTERS, 1972, 20 (12) :492-+
[8]   Magnetic properties of core-shell type Fe16N2 nanoparticles [J].
Kita, Eiji ;
Shibata, K. ;
Yanagihara, H. ;
Sasaki, Y. ;
Kishimoto, M. .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2007, 310 (02) :2411-2413
[9]   Theoretical analysis of highly spin-polarized transport in the iron nitride Fe4N [J].
Kokado, Satoshi ;
Fujima, Nobuhisa ;
Harigaya, Kikuo ;
Shimizu, Hisashi ;
Sakuma, Akimasa .
PHYSICAL REVIEW B, 2006, 73 (17)
[10]   Challenge to the Synthesis of α"-Fe16N2 Compound Nanoparticle with High Saturation Magnetization for Rare Earth Free New Permanent Magnetic Material [J].
Ogawa, Tomoyuki ;
Ogata, Yasunobu ;
Gallage, Ruwan ;
Kobayashi, Naoya ;
Hayashi, Naoaki ;
Kusano, Yoshihiro ;
Yamamoto, Shinpei ;
Kohara, Kaori ;
Doi, Masaaki ;
Takano, Mikio ;
Takahashi, Migaku .
APPLIED PHYSICS EXPRESS, 2013, 6 (07)