Selective synthesis under microwave irradiation of carbohydrate derivatives containing unsaturated systems

被引：18
|
作者：
Andrade, Marta M. [1 ]
Barros, Maria Teresa [1 ]
Rodrigues, Paula [1 ]
机构：
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, REQUIMTE, CQFB,Dept Quim, P-2829516 Caparica, Portugal
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 2007卷 / 22期
关键词：
microwave; selective methods; carbohydrates; esterification; wittig reactions;
D O I：
10.1002/ejoc.200700154
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The selective synthesis of sugars containing vinyl ester- and vinyl ether-type side chains was developed by means of esterification and Wittig olefination procedures. The studies were focused on the anomeric position of D-xylose and on the primary carbon positions of D-glucose and sucrose. Microwave heating was used in both cases, and the results obtained show the usefulness of microwave irradiation for the development of cleaner technologies in carbohydrate chemistry. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007).
引用
收藏
页码：3655 / 3668
页数：14
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