Impedance of a passive iron electrode in a solution containing a reducing agent

被引：3
作者：
Klyuev, AL
Rotenbergb, ZA
Batrakov, VV
机构：
[1] Russian Acad Sci, Frumkin Inst Electrochem, Moscow 119071, Russia
[2] Moscow State Pedag Univ, Moscow 119882, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2005年 / 41卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
impedance; passive iron electrode;
D O I：
10.1007/s11175-005-0010-6
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Frequency dependences of impedance of a passive iron electrode in 0.5 M Na2SO4 solutions with and without 0.01 M K-4[Fe(CN)(6)] are obtained by a pulsed method and the Fourier transform. At 1-1000 Hz, the results in 0.5 M Na2SO4 satisfactorily agree with our previous results obtained by a lock-in method. With the [Fe(CN)(6)](4-) ions present, the impedance decreases faster at lower frequencies. The impedance of the oxide film/solution interface relaxes longer the film impedance. These conclusions are similar to those obtained earlier.
引用
收藏
页码：87 / 90
页数：4
相关论文
共 24 条
  • [21] Impedance measurement of thin film SnO2 electrode in a sodium sulfate electrolyte containing SnSO4
    Hirano, K
    Takikawa, H
    Jou, M
    Mizusaki, J
    Tagawa, H
    DENKI KAGAKU, 1996, 64 (01): : 37 - 40
  • [22] CAPACITANCE OF THE GOLD ELECTRODE IN 0.5 M H2SO4 SOLUTION - AC-IMPEDANCE STUDIES
    PIELA, B
    WRONA, PK
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 388 (1-2): : 69 - 79
  • [23] Sustained Immersion Tin Deposition on Copper from Choline Chloride Based Aqueous Solution without Reducing Agent
    Wang, Yurong
    He, Jiawei
    Wang, Wenchang
    Naotoshi, Mitsuzaki
    Chen, Zhidong
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (08) : D295 - D299
  • [24] Electrochemical corrosion behavior of Al7075 rotating disc electrode in neutral solution containing l-glutamine as a green inhibitor
    Ashassi-Sorkhabi, H.
    Asghari, E.
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 2010, 40 (03) : 631 - 637
123