Novel synthesis of polyarylenesulfonium cations through a multi-electron transfer process

被引：0

作者：

Tsuchida, E ^{[1
]}

Miyatake, K ^{[1
]}

机构：

[1] Waseda Univ, Adv Res Inst Sci & Engn, Dept Polymer Chem, Tokyo 169, Japan

来源：

CHINESE JOURNAL OF POLYMER SCIENCE | 1998年 / 16卷 / 02期

关键词：

oxidative polymerization; multi-electron transfer; sulfonium cation; poly(thio phenylene);

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The oxidative polymerization of aryl sulfoxides provides a novel polysulfonium compound, poly(methylsulfonio-1,4-phenylenethio-1,4-phenylene cation) in quantitative yield. The polymerization proceeds efficiently in an acidic solution under atmospheric conditions. Oxygen, chemical and electrochemical oxidations are available. Vanadyl acetylacetonate and cerium ammonium nitrate act as an effective catalyst for the oxygen oxidative polymerization. The polymerization mechanism involves multielectron oxidation of the sulfides followed by successive electrophilic substitution. The resulting polyarylenesulfonium cations are useful as a soluble precursor for the synthesis of high molecular weight (M-w > 10(5)) poly(thio arylne)s.

引用

页码：106 / 116

页数：11

共 50 条

[1] Novel synthesis of polyarylenesulfonium cations through a multi-electron transfer process
Tsuchida, Eishun
Miyatake, Kenji
Chinese Journal of Polymer Science (English Edition), 16 (02): : 106 - 116
[2] NOVEL SYNTHESIS OF POLYARYLENESULFONIUM CATIONS THROUGH A MULTI-ELECTRON TRANSFER PROCESS
TSUCHIDA Eishun
MIYATAKE Kenji
Chinese Journal of Polymer Science, 1998, (02) : 106 - 116
[3] Polythiophenylene synthesis through multi-electron transfer process
Oyaizu, K
Tsuchida, E
MACROMOLECULAR SYMPOSIA, 2003, 204 : 19 - 25
[4] Multi-electron transfer process of vanadyl complexes for molecular conversion
Tsuchida, E.
Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Materials Science and Engineering, 1994, 71
[5] Multi-electron transfer process for the degradation of toxic organophosphorus contaminants
Santos, Stephanie
Obare, Sherine
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
[6] Synthesis of a multi-electron transfer reagent using click chemistry
Beagan, Daniel
Ringo, Jessica
Manamperi, Hemanthi
Krause, Jeanette
Connick, William
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
[7] Multi-electron transfer process of a vanadium dinuclear complex for molecular conversions
Tsuchida, E
Yamamoto, K
Oyaizu, K
METAL-CONTAINING POLYMERIC MATERIALS, 1996, : 139 - 149
[8] Synthesis and electrochemical properties of intramolecular multi-electron transfer probe compounds
Wang, ZH
Chen, KC
Tian, H
DYES AND PIGMENTS, 1996, 30 (04) : 261 - 269
[9] Multi-electron transfer System for the Reduction of Chromium
Saeed, Tahseen
Obare, Sherine
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
[10] Environmental remediation of perfluorooctanoic acid using a novel multi-electron transfer system
Saeed, Tahseen
Obare, Sherine
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257

← 1 2 3 4 5 →