Avocado seed powder: characterization and its application for crystal violet dye removal from aqueous solutions

被引:68
作者
Bazzo, Alexandre [1 ]
Adebayo, Matthew A. [2 ]
Dias, Silvio L. P. [1 ]
Lima, Eder C. [1 ]
Vaghetti, Julio C. P. [1 ]
de Oliveira, Eduardo R. [1 ]
Leite, Anderson J. B. [1 ]
Pavan, Flavio A. [3 ]
机构
[1] Fed Univ Rio Grande Sul UFRGS, Inst Chem, Av Bento Goncalves 9500,POB 15003, BR-91501970 Porto Alegre, RS, Brazil
[2] Fed Univ Agr, Dept Chem, PMB 2240, Abeokuta, Ogun State, Nigeria
[3] Fed Univ Pampa UNIPAMPA, Inst Chem, Bage, RS, Brazil
关键词
Avocado seed; Adsorption; Equilibrium; Kinetic; Crystal violet; BLUE MX-R; ACTIVATED CARBON; MALACHITE GREEN; METHYLENE-BLUE; AQAI STALKS; ADSORPTION; EQUILIBRIUM; BIOSORPTION; KINETICS; ISOTHERM;
D O I
10.1080/19443994.2015.1074621
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This study presents removal of crystal violet (CV) dye from aqueous solutions using solid food waste, avocado kernel seed powder (ASP). ASP was used in the native form for biosorption study. The effects of different experimental conditions such as pH of the solution, initial dye concentration, contact time, and temperature were investigated using batch study. Maximum removal of CV (95.9mgg(-1)) by ASP (100mg) was observed at pH 7 and 55 degrees C. The kinetics data were evaluated using pseudo-first-order, pseudo-second-order, and general-order kinetic adsorption models. The general-order kinetic adsorption model gave the best description of the biosorption kinetic of CV onto ASP biosorbent. Similarly, the intraparticle diffusion plots showed three linear portions during biosorption process. Freundlich, Langmuir, and Liu models were used to analyze the isothermal data; Liu equilibrium model gave the best fit of the isothermal data of CV biosorption onto ASP. The calculations from thermodynamic studies showed that CV biosorption onto ASP was an exothermic process and a feasible process. The combined data showed that avocado seed powder could be efficiently utilized for the treatment of dyes-rich wastewaters.
引用
收藏
页码:15873 / 15888
页数:16
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