Hydrogen adsorption and storage on porous materials

被引：425
作者：
Thomas, K. Mark [1 ]
机构：
[1] Newcastle Univ, Sch Nat Sci, No Carbon Res Labs, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
来源：
CATALYSIS TODAY | 2007年 / 120卷 / 3-4期
关键词：
hydrogen; adsorption; storage; carbons; metal organic frameworks; porous materials;
D O I：
10.1016/j.cattod.2006.09.015
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The development of safe and efficient methods of hydrogen storage is a prerequisite for the use of hydrogen with fuel cells for transport applications. In this paper, results available for adsorption of hydrogen on porous materials, ranging from activated carbons to metal organic framework materials, are discussed. The results indicate that up to similar to 5 and similar to 7.5 wt% of hydrogen can be stored on porous carbon and metal organic framework materials, respectively, at 77 K. The amounts of hydrogen adsorbed on porous materials at ambient temperatures and high pressures are much lower (less than or similar to 0.5 wt%). The strong temperature dependence of hydrogen physisorption on porous materials is a limitation in the application of this method for hydrogen storage in addition to storage capacity requirements. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：389 / 398
页数：10
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