A catalytic and transition metal-free method for the chemoselective oxidation of alcohols to their corresponding carbonyl compounds using periodic acid or iodic acid in the presence of a catalytic amount of KBr

被引：41
作者：
Zolfigol, Mohammad Ali
Shirini, Farhad
Chehardoli, Gholamabbas
Kolvari, Eskandar
机构：
[1] Bu Ali Sina Univ, Fac Chem, Hamadan, Iran
[2] Guilan Univ, Coll Sci, Dept Chem, Rasht, Iran
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 265卷 / 1-2期
关键词：
periodic acid; iodic acid; alcohols; chemoselective oxidation; catalytic amount of KBr; oxidation;
D O I：
10.1016/j.molcata.2006.10.038
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Chemoselective oxidation of various alcohols was proceeded by using a catalytic amount of KBr in the presence of periodic acid or iodic acid and wet SiO2 under mild and heterogeneous conditions with moderate to excellent yields. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：272 / 275
页数：4
相关论文
共 34 条
[1]  
ANELLI PL, 1987, J ORG CHEM, V52, P2559
[2]   Microwave-assisted synthesis of N-arylglycines:: Improvement of sydnone synthesis [J].
Azarifar, D ;
Bosra, HG ;
Zolfigol, MA ;
Tajbaksh, M .
HETEROCYCLES, 2006, 68 (01) :175-181
[3]   A new and highly effective method for catalytic oxidation of alcohols to the corresponding carbonyl compounds using the tris[(2-oxazolinyl)phenolatolmanganese(III)/Oxone®/n-Bu4NBr oxidation system [J].
Bagherzadeh, M .
TETRAHEDRON LETTERS, 2003, 44 (50) :8943-8945
[4]   Catalytic properties of several palladium complexes covalently anchored onto silica for the aerobic oxidation of alcohols [J].
Choudhary, D ;
Paul, S ;
Rajive, GA ;
Clark, JH .
GREEN CHEMISTRY, 2006, 8 (05) :479-482
[5]   Bromide ions and methyltrioxorhenium as cocatalysts for hydrogen peroxide oxidations and brominations [J].
Espenson, JH ;
Zhu, ZL ;
Zauche, TH .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (04) :1191-1196
[6]   Catalytic oxidation of alcohols using molecular oxygen mediated by poly(ethylene glycol)-supported nitroxyl radicals [J].
Ferreira, P ;
Phillips, E ;
Rippon, D ;
Tsang, SC .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2005, 61 (3-4) :206-211
[7]   Heteropoly acids, their salts and polyoxometalates as heterogenous, efficient and eco-friendly catalysts in organic reactions: Some recent advances [J].
Firouzabadi, H. ;
Jafari, A. A. .
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2005, 2 (02) :85-114
[8]   Iodic acid (HIO3) [J].
Ghorbani-Choghamarani, Arash .
SYNLETT, 2006, (14) :2347-2348
[9]  
Hashemi MM, 2005, ACTA CHIM SLOV, V52, P86
[10]   Pyridinium chlorochromate catalyzed oxidation of alcohols to aldehydes and ketones with periodic acid [J].
Hunsen, M .
TETRAHEDRON LETTERS, 2005, 46 (10) :1651-1653
1234