A self-assembled M2L4 cage incorporating electron-rich 9-(1,3-dithiol-2-ylidene)fluorene units

被引：19
作者：
Croue, V. [1 ]
Krykun, S. [1 ,2 ]
Allain, M. [1 ]
Morille, Y. [1 ]
Aubriet, F. [3 ]
Carre, V. [3 ]
Voitenko, Z. [2 ]
Goeb, S. [1 ]
Salle, M. [1 ]
机构：
[1] Univ Angers, Lab MOLTECH Anjou, CNRS UMR 6200, 2 Bd Lavoisier, F-49045 Angers, France
[2] Taras Shevchenko Natl Univ Kyiv, 64-13 Volodymyrska St, UA-01033 Kiev, Ukraine
[3] Univ Lorraine, LCP A2MC,ICPM, FR Inst Jean Barriol Chim & Phys Mol & Biomol 284, FR Reseau Natl Spectrometrie Masse FT ICR Tres Ha, 1 Blvd Arago, F-57078 Metz 03, France
来源：
NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 09期
关键词：
COORDINATION CAGES; MOLECULAR CAPSULE; COMPLEXES; GUESTS; METALLACYCLES; DISCRETE; CLICK;
D O I：
10.1039/c7nj00062f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An electron-rich redox-active M2L4 cage is depicted. The cage is constructed through coordination driven self-assembly of a 9-(1,3-dithiol-2-ylidene)fluorene bis-pyridyl ligand in the presence of the Pd(BF4)(2)(CH3CN)(4) complex. The corresponding discrete structure has been fully characterized in the solution as well in the solid state (crystal structure), showing notably that each of the four ligands surrounding the cavity can be reversibly oxidized upon a one electron process.
引用
收藏
页码：3238 / 3241
页数：4
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