Syntheses, structure, and properties of a manganese-calcium cluster containing a Mn4Ca2 core

被引：35
|
作者：
Jerzykiewicz, Lucjan B.
Utko, Jozef
Duczmal, Marek
Sobota, Piotr
机构：
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
[2] Wroclaw Tech Univ, Fac Chem, PL-50370 Wroclaw, Poland
来源：
DALTON TRANSACTIONS | 2007年 / 08期
关键词：
D O I：
10.1039/b613320g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We describe here a novel, simple, efficient self-assembly method for the in situ generation of [Mn4Cl4(mu-OCH2CH2OMe)(4)(EtOH)(4)] (1) and [Mn-4(p-Cl)Cl-3(p-OCH2CH2OMe)(4)(HOCH2CH2OMe)(3)](2) (2) cubane-type compounds which react readily with calcium species to form cluster [Mn4Ca2Cl4(mu-OCH2CH2OMe)(8)] (3), the calcium atoms attached to the Mn-4 unit of 3 flatten out the cubane inducing significant conformational changes.
引用
收藏
页码：825 / 826
页数：2
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