A simple method for controlling dendritic architecture and diversity:: A parallel monomer combination approach

被引：43

作者：

Freeman, AW ^{[1
]}

Chrisstoffels, LAJ ^{[1
]}

Fréchet, JMJ ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2000年 / 65卷 / 22期

关键词：

D O I：

10.1021/jo005592i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel parallel monomer combination approach to manipulating the architectural disposition of dendritic macromolecules is described. It harnesses the synthetic speed and power of the double-stage convergent growth approach and classical parallel synthesis to prepare diverse series of dendrimers that possess a predetermined number and arrangement of "internal" functional moieties. This methodology is applied for the preparation of a novel family of poly(benzyl ether) dendrimers possessing 1-15 "internal" allyloxy groups, which are displayed in a highly controlled, layer-specific, generational manner.

引用

页码：7612 / 7617

页数：6

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