Nanostructured and nanoporous LiFePO4 and LiNi0.5Mn1.5O4-δ as cathode materials for lithium-ion batteries

被引：14
作者：
Kraas, Sebastian [1 ]
Vijn, Annalena [1 ]
Falk, Mareike [2 ]
Ufer, Boris [1 ]
Luerssen, Bjoern [2 ]
Janek, Juergen [2 ]
Froeba, Michael [1 ]
机构：
[1] Univ Hamburg, Inst Inorgan & Appl Chem, D-20146 Hamburg, Germany
[2] Univ Giessen, Inst Phys Chem, D-35392 Giessen, Germany
来源：
PROGRESS IN SOLID STATE CHEMISTRY | 2014年 / 42卷 / 04期
关键词：
Cathode materials; Lithium ion battery; Spinel; Thin films; Lithium iron phosphate; Lithium nickel manganese oxide; LNMO; LFP; POROUS SINGLE-CRYSTALS; THIN-FILM ELECTRODES; ELECTROCHEMICAL PERFORMANCE; MESOPOROUS SILICA; SURFACE-AREA; TEXTURAL PARAMETERS; DOUBLE SUBSTITUTION; POSITIVE-ELECTRODE; SPINEL OXIDES; CARBON;
D O I：
10.1016/j.progsolidstchem.2014.04.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Recent developments in the synthesis of nanostructured cathode materials are reviewed for the two prominent compounds LiFePO4 and LiNi0.5Mn1.5O4, and own results on LiFePO4 and LiNi0.5Mn1.5O4 with different microstructure are presented. The synthesis of LiFePO4 composites with porous carbons and the scale up of their synthesis is reported, as well as of nanoporous materials. In the case of LiNi0.5Mn1.5O4 the formation of deteriorating cathode surface films is studied with thin film electrodes and ToF-SIMS depth profiling. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：218 / 241
页数：24
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