Mixed metal-organic nanocapsules

被引：213
|
作者：
Jin, Ping [2 ]
Dalgarno, Scott J. [1 ]
Atwood, Jerry L. [2 ]
机构：
[1] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland
[2] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
来源：
COORDINATION CHEMISTRY REVIEWS | 2010年 / 254卷 / 15-16期
关键词：
Supramolecular chemistry; Coordination chemistry; Self-assembly; Host-guest chemistry; Metal-organic nanocapsules; MOLECULAR CAPSULES; RESORCINARENE CAPSULES; GUEST MOLECULES; COORDINATION; ASSEMBLIES; INTERIOR; EXCHANGE; ROBUST; POLAR; WATER;
D O I：
10.1016/j.ccr.2010.04.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The formation of hydrogen-bonded nanometer scale capsules from C-methylresorcin[4]arene represented a new area of research within the broad field of supramolecular chemistry. The related pyrogallol[4]arenes form nanocapsules of similar dimensions and this research now extends into the formation of novel metal-organic nanocapsules (MONCs). These relatively new systems are described here, with particular focus on recent advances in the formation of MONCs that are seamed together by more than one type of metal ion. This chemistry holds great potential for the isolation of designer materials that allow for enhanced control over the ratios of metal ions within these supramolecular assemblies. Published by Elsevier B.V.
引用
收藏
页码：1760 / 1768
页数：9
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