Microfluidic-based Synthesis of Covalent Organic Frameworks (COFs): A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

被引:7
作者
Abrishamkar, Afshin [1 ]
Rodriguez-San-Miguel, David [2 ]
Rodriguez Navarro, Jorge Andres [3 ]
Rodriguez-Trujillo, Romen [4 ]
Amabilino, David B. [5 ]
Mas-Balleste, Ruben [2 ]
Zamora, Felix [2 ,6 ,7 ]
deMello, Andrew J. [1 ]
Puigmarti-Luis, Josep [1 ]
机构
[1] Swiss Fed Inst Technol, Inst Chem & Bioengn, Dept Chem & Appl Biosci, Zurich, Switzerland
[2] Univ Autonoma Madrid, Dept Quim Inorgan, Madrid, Spain
[3] Univ Granada, Dept Quim Inorgan, Granada, Spain
[4] CSIC, Inst Ciencia Mat Barcelona ICMAB, Barcelona, Spain
[5] Univ Nottingham, Sch Chem, Nottingham, England
[6] Univ Autonoma Madrid, Condensed Matter Phys Ctr IFMAC, Madrid, Spain
[7] IMDEA Nanociencia, Inst Madrileno Estudios Avanzados Nanociencia, Madrid, Spain
来源
JOVE-JOURNAL OF VISUALIZED EXPERIMENTS | 2017年 / 125期
基金
瑞士国家科学基金会;
关键词
Chemistry; Issue; 125; Covalent organic frameworks; porous materials; crystalline material; microfluidic synthesis; drawing fibers; 3D structures; CRYSTALLINE; STORAGE; GROWTH;
D O I
10.3791/56020
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Covalent Organic Frameworks (COFs) are a class of porous covalent materials which are frequently synthesized as unprocessable crystalline powders. The first COF was reported in 2005 with much effort centered on the establishment of new synthetic routes for its preparation. To date, most available synthetic methods for COF synthesis are based on bulk mixing under solvothermal conditions. Therefore, there is increasing interest in developing systematic protocols for COF synthesis that provide for fine control over reaction conditions and improve COF processability on surfaces, which is essential for their use in practical applications. Herein, we present a novel microfluidic-based method for COF synthesis where the reaction between two constituent building blocks, 1,3,5-benzenetricarbaldehyde (BTCA) and 1,3,5-tris(4-aminophenyl) benzene (TAPB), takes place under controlled diffusion conditions and at room temperature. Using such an approach yields sponge-like, crystalline fibers of a COF material, hereafter called MF-COF. The mechanical properties of MF-COF and the dynamic nature of the approach allow the continuous production of MF-COF fibers and their direct printing onto surfaces. The general method opens new potential applications requiring advanced printing of 2D or 3D COF structures on flexible or rigid surfaces.
引用
收藏
页数:8
相关论文
共 23 条
[1]   Microfluidic Pneumatic Cages: A Novel Approach for In-chip Crystal Trapping, Manipulation and Controlled Chemical Treatment [J].
Abrishamkar, Afshin ;
Paradinas, Markos ;
Bailo, Elena ;
Rodriguez-Trujillo, Romen ;
Pfattner, Raphael ;
Rossi, Rene M. ;
Ocal, Carmen ;
deMello, Andrew J. ;
Amabilino, David B. ;
Puigmarti-Luis, Josep .
JOVE-JOURNAL OF VISUALIZED EXPERIMENTS, 2016, (113)
[2]   Two-dimensional Covalent Organic Framework Thin Films Grown in Flow [J].
Bisbey, Ryan P. ;
DeBlase, Catherine R. ;
Smith, Brian J. ;
Dichtel, William R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (36) :11433-11436
[3]   Porous, crystalline, covalent organic frameworks [J].
Côté, AP ;
Benin, AI ;
Ockwig, NW ;
O'Keeffe, M ;
Matzger, AJ ;
Yaghi, OM .
SCIENCE, 2005, 310 (5751) :1166-1170
[4]   Chemical sensing in two dimensional porous covalent organic nanosheets [J].
Das, Gobinda ;
Biswal, Bishnu P. ;
Kandambeth, Sharath ;
Venkatesh, V. ;
Kaur, Gagandeep ;
Addicoat, Matthew ;
Heine, Thomas ;
Verma, Sandeep ;
Banerjee, Rahul .
CHEMICAL SCIENCE, 2015, 6 (07) :3931-3939
[5]   Direct On-Surface Patterning of a Crystalline Laminar Covalent Organic Framework Synthesized at Room Temperature [J].
de la Pena Ruigomez, Alejandro ;
Rodriguez-San-Miguel, David ;
Stylianou, Kyriakos C. ;
Cavallini, Massimiliano ;
Gentili, Denis ;
Liscio, Fabiola ;
Milita, Silvia ;
Maria Roscioni, Otello ;
Luisa Ruiz-Gonzalez, Maria ;
Carbonell, Carlos ;
Maspoch, Daniel ;
Mas-Balleste, Ruben ;
Luis Segura, Jose ;
Zamora, Felix .
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (30) :10666-10670
[6]   Covalent organic frameworks (COFs): from design to applications [J].
Ding, San-Yuan ;
Wang, Wei .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (02) :548-568
[7]   Rapid prototyping of microfluidic systems in poly(dimethylsiloxane) [J].
Duffy, DC ;
McDonald, JC ;
Schueller, OJA ;
Whitesides, GM .
ANALYTICAL CHEMISTRY, 1998, 70 (23) :4974-4984
[8]   Designed synthesis of 3D covalent organic frameworks [J].
El-Kaderi, Hani M. ;
Hunt, Joseph R. ;
Mendoza-Cortes, Jose L. ;
Cote, Adrien P. ;
Taylor, Robert E. ;
O'Keeffe, Michael ;
Yaghi, Omar M. .
SCIENCE, 2007, 316 (5822) :268-272
[9]   Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications [J].
Furukawa, Hiroyasu ;
Yaghi, Omar M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8875-8883
[10]   Conjugated organic framework with three-dimensionally ordered stable structure and delocalized π clouds [J].
Guo, Jia ;
Xu, Yanhong ;
Jin, Shangbin ;
Chen, Long ;
Kaji, Toshihiko ;
Honsho, Yoshihito ;
Addicoat, Matthew A. ;
Kim, Jangbae ;
Saeki, Akinori ;
Ihee, Hyotcherl ;
Seki, Shu ;
Irle, Stephan ;
Hiramoto, Masahiro ;
Gao, Jia ;
Jiang, Donglin .
NATURE COMMUNICATIONS, 2013, 4