Synthesis and characterization of herbicidal ionic liquids based on (4-chloro-2-methylphenoxy)acetate and phenoxyethylammonium

被引：3
|
作者：
Ciarka, Kamil [1 ,2 ]
Olszewski, Radoslaw [1 ,2 ]
Praczyk, Tadeusz [3 ]
Pernak, Juliusz [4 ]
机构：
[1] Adam Mickiewicz Univ, Fac Chem, Ul Uniwersytetu Poznanskiego 8, PL-61614 Poznan, Poland
[2] PPC ADOB, Ul Kolodzieja 11, PL-61070 Poznan, Poland
[3] Natl Res Inst, Inst Plant Protect, Ul Wegorka 20, PL-60318 Poznan, Poland
[4] Poznan Univ Tech, Dept Chem Technol, Ul Berdychowo 4, PL-60965 Poznan, Poland
来源：
CHEMICAL PAPERS | 2021年 / 75卷 / 07期
关键词：
Ionic liquids; Herbicides; Phenoxyethylammonium; MCPA; Domiphen;
D O I：
10.1007/s11696-021-01610-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ten ionic liquids containing the (4-chloro-2-methylphenoxy)acetate (MCPA) anion and domiphen derived phenoxyethylammonium cation were synthesized. The obtained compounds differed in terms of the substitution of the phenoxyethylammonium group in the ring (the presence of a methyl group in the meta or para positions and the presence of chlorine in the para position) as well as the length of the alkyl chain (from hexyl to tetradecyl). The basic physicochemical properties of the obtained ionic liquids (solubility and thermal stability) were characterized and their structures were confirmed. The herbicidal activity of the compounds was tested under greenhouse conditions using cornflower (Centaurea cyanus L.) as the test plant.
引用
收藏
页码：3607 / 3615
页数：9
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