Total synthesis of the marine sesquiterpene hydroquinones zonarol and isozonarol and the sesquiterpene quinones zonarone and isozonarone

被引：21
|
作者：
Schröder, J [1 ]
Magg, C [1 ]
Seifert, K [1 ]
机构：
[1] Univ Bayreuth, Lehrstuhl Organ Chem 12, D-95440 Bayreuth, Germany
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 29期
关键词：
terpenes; phenols; quinones;
D O I：
10.1016/S0040-4039(00)00891-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The total synthesis of the naturally occurring sesquiterpene hydroquinones zonarol and isozonarol and the sesquiterpene quinones zonarone and isozonarone was achieved starting from beta-ionone, which was transformed via (+)-albicanic acid to (+)-albicanal and (-)-drim-7-en-11-al. Coupling of the aldehydes with lithiated hydroquinone ethers and further modification of the coupling products led to the target molecules. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：5469 / 5473
页数：5
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