Total synthesis of the marine sesquiterpene hydroquinones zonarol and isozonarol and the sesquiterpene quinones zonarone and isozonarone

被引：21

作者：

Schröder, J ^{[1
]}

Magg, C ^{[1
]}

Seifert, K ^{[1
]}

机构：

[1] Univ Bayreuth, Lehrstuhl Organ Chem 12, D-95440 Bayreuth, Germany

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 29期

关键词：

terpenes; phenols; quinones;

D O I：

10.1016/S0040-4039(00)00891-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The total synthesis of the naturally occurring sesquiterpene hydroquinones zonarol and isozonarol and the sesquiterpene quinones zonarone and isozonarone was achieved starting from beta-ionone, which was transformed via (+)-albicanic acid to (+)-albicanal and (-)-drim-7-en-11-al. Coupling of the aldehydes with lithiated hydroquinone ethers and further modification of the coupling products led to the target molecules. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：5469 / 5473

页数：5

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