The Heck Reaction Applied to 1,3-and 1,2-Unsaturated Derivatives, a Way towards Molecular Complexity

被引：57
作者：
Deagostino, Annamaria [1 ]
Prandi, Cristina [1 ]
Tabasso, Silvia [1 ]
Venturello, Paolo [1 ]
机构：
[1] Univ Turin, Dipartimento Chim Gen & Chim Organ, I-10125 Turin, Italy
来源：
MOLECULES | 2010年 / 15卷 / 04期
关键词：
Mizoroki-Heck reaction; palladium; 1,2-dienes; 1,3-dienes; PALLADIUM-CATALYZED HETEROANNULATION; FUNCTIONALLY-SUBSTITUTED ARYL; ALDER CASCADE PROCESSES; EFFICIENT CATALYSTS; CYCLIZATION; ALLENES; CARBON; PALLADACYCLES; INDOLE-2,3-QUINODIMETHANES; CARBOANNULATION;
D O I：
10.3390/molecules15042667
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
This review is an overview of the last ten years' use of the Mizoroki-Heck coupling applied to 1,2- and 1,3-dienes. Since both these systems form pi-allyl palladium intermediates in Pd(0) coupling, they show particular chemical behavior. Many examples of 1,2-dienes Heck reactions are presented. 1,2-Dienes are important substrates because of their high reactivity that makes them useful building blocks for the synthesis of biologically relevant structures.
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页码：2667 / 2685
页数：19
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