Infrared Induced Reactivity on the Surface of Isolated Size-Selected Clusters: Dissociation of N2O on Rhodium Clusters

被引:71
作者
Hamilton, Suzanne M. [1 ]
Hopkins, W. Scott [1 ]
Harding, Dan J. [2 ,3 ,4 ]
Walsh, Tiffany R. [2 ,3 ]
Gruene, Philipp [4 ]
Haertelt, Marko [4 ]
Fielicke, Andre [4 ]
Meijer, Gerard [4 ]
Mackenzie, Stuart R. [1 ]
机构
[1] Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
[2] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England
[3] Univ Warwick, Ctr Comp Sci, Coventry CV4 7AL, W Midlands, England
[4] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
基金
英国工程与自然科学研究理事会;
关键词
VIBRATIONAL SPECTROSCOPY; NITROUS-OXIDE; GAS-PHASE; ADSORPTION; CATIONS; CO; DECOMPOSITION; DESORPTION; COMPLEXES; IONS;
D O I
10.1021/ja907496c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Multiple photon infrared excitation of size-selected Rh6N2O+ clusters drives surface chemistry resulting in partially oxidized Clusters.
引用
收藏
页码:1448 / +
页数:4
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