Precise one-pot synthesis of fully conjugated end-functionalized star polymers containing poly(fluorene-2,7-vinylene) (PFV) arms

被引：19
作者：
Nomura, Kotohiro [1 ,2 ]
Haque, Tahmina [1 ]
Miwata, Tomohiro [1 ]
Inagaki, Akiko [1 ]
Takamizu, Kenji [1 ]
机构：
[1] Tokyo Metropolitan Univ, Dept Chem, Fac Sci & Engn, Hachioji, Tokyo 1920397, Japan
[2] Japan Sci & Technol Agcy JST, Adv Catalyt Transformat Carbon Utilizat ACT C, Saitama 3320012, Japan
来源：
POLYMER CHEMISTRY | 2015年 / 6卷 / 03期
基金：
日本科学技术振兴机构;
关键词：
DIENE METATHESIS POLYMERIZATION; LIGHT-EMITTING-DIODES; GRAFTING POLY(ETHYLENE GLYCOL); ALTERNATING BLOCK-COPOLYMERS; HETEROJUNCTION SOLAR-CELLS; COMBINED OLEFIN METATHESIS; CHARGE-TRANSFER; WHITE ELECTROLUMINESCENCE; MULTIBLOCK COPOLYMERS; ADMET POLYMERIZATION;
D O I：
10.1039/c4py01287a
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A facile, precise one-pot synthesis of end-functionalized star (triarm) polymers consisting of poly(9,9-di-n-octylfluorene-2,7-vinylene)s (PFVs), the triblock copolymers [by incorporation of tri(2,5-dialkoxy-1,4-phenylene vinylene) or terthiophene units as the middle segment], has been achieved by olefin metathesis followed by Wittig-type coupling; effects of the PFV conjugation length, the middle segment and the end groups on the emission properties have been studied.
引用
收藏
页码：380 / 388
页数：9
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