Sorption-enhanced membrane materials for gas separation: a road less traveled

被引：28

作者：

Omidvar, Maryam ^{[1
]}

Hien Nguyen ^{[1
]}

Liu, Junyi ^{[1
]}

Lin, Haiqing ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem & Biol Engn, Buffalo, NY 14260 USA

来源：

CURRENT OPINION IN CHEMICAL ENGINEERING | 2018年 / 20卷

基金：

美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; GRAPHENE OXIDE MEMBRANES; MIXED MATRIX MEMBRANES; FACILITATED TRANSPORT; ETHYLENE/ETHANE SEPARATION; GLASSY PERFLUOROPOLYMERS; POLY(ETHYLENE OXIDE); SELECTIVE ADSORPTION; TRADEOFF RELATIONS; POLYMER MEMBRANES;

D O I：

10.1016/j.coche.2018.02.003

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Solubility and diffusivity constitute two vertically tunable parameters for designing high-performance membrane materials for gas separation. The latter approach has received great attention, yielding a wealth of size-sieving materials reported in the literature. By contrast, this review highlights recent achievements of sorption-enhanced materials with superior gas separation performance, including fluorinated polymers for He/gas and gas/CH4 separations, and polar polymers and mixed-matrix materials comprising metalorganic frameworks for olefin/paraffin separations. The undervalued solubility and solubility selectivity are powerful tools in designing materials with superior separation properties and good resistance to plasticization caused by condensable components in the feed, which, otherwise, would decrease gas selectivity.

引用

页码：50 / 59

页数：10

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