Facile preparation, characterization and performance of noncovalently functionalized graphene/epoxy nanocomposites with poly(sodium 4-styrenesulfonate)

被引：59
|
作者：
Li, Yuchao [1 ,2 ,3 ,4 ]
Tang, Jianguo [1 ,2 ]
Huang, Linjun [1 ,2 ]
Wang, Yao [1 ,2 ]
Liu, Jixian [1 ,2 ]
Ge, Xiangcai [3 ]
Tjong, Sie Chin [4 ]
Li, Robert Kwok Yiu [4 ]
Belfiore, Laurence A. [1 ,2 ,5 ]
机构：
[1] Qingdao Univ, Natl Base Int Sci & Technol Cooperat Hybrid Mat, Dept Chem & Environm, Qingdao 266071, Peoples R China
[2] Qingdao Univ, Inst Hybrid Mat, Qingdao 266071, Peoples R China
[3] Liaocheng Univ, Dept Mat Sci & Engn, Liaocheng 252059, Shandong, Peoples R China
[4] City Univ Hong Kong, Dept Phys & Mat Sci, Kowloon, Hong Kong, Peoples R China
[5] Colorado State Univ, Dept Chem & Biol Engn, Ft Collins, CO 80523 USA
来源：
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING | 2015年 / 68卷
关键词：
Polymer-matrix composites (PMCs); Mechanical properties; Electrical properties; MECHANICAL-PROPERTIES; OXIDE; GRAPHITE; NANOSHEETS; REDUCTION; POLYPROPYLENE; CONDUCTIVITY; DISPERSIONS; EXFOLIATION; PERCOLATION;
D O I：
10.1016/j.compositesa.2014.09.016
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Graphene was noncovalently functionalized with poly(sodium 4-styrenesulfonate) (PSS) and then successfully incorporated into the epoxy resin via in situ polymerization to form functional and structural nanocomposites. The morphology and structure of PSS modified graphene (PSS-g) were characterized with transmission electron microscopy, X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. The effects of PSS-g additions on tensile, electrical and thermal properties of the epoxy/graphene nanocomposites were studied. Noncovalent functionalization improved interfacial bonding between the epoxy matrix and graphene, leading to enhanced tensile strength and modulus of resultant nanocomposites. The PSS-g additions also enhanced electrical properties of the epoxy/PSS-g nanocomposites, resulting in a lower percolation threshold of 1.2 wt%. Thermogravimetric and differential scanning calorimetric results showed the occurrence of a two-step decomposition process for the epoxy/PSS-g nanocomposites. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1 / 9
页数：9
相关论文
共 50 条
  • [41] Poly(sodium 4-styrenesulfonate) modified carbon nanoparticles by a thermo-mechanical technique and its reinforcement in natural rubber latex
    He, Xuelian
    Peng, Zheng
    Yu, Na
    Han, Jingjie
    Wu, Chifei
    COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (14) : 3027 - 3032
  • [42] Preparation and characterization of melt-blended graphene nanosheets-poly(vinylidene fluoride) nanocomposites with enhanced properties
    El Achaby, M.
    Arrakhiz, F. Z.
    Vaudreuil, S.
    Essassi, E. M.
    Qaiss, A.
    Bousmina, M.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 127 (06) : 4697 - 4707
  • [43] Preparation and Characterization of Epoxy Nanocomposites Containing Surface-Modified Graphene Oxide
    Liu, Tianxi
    Zhao, Zishuai
    Tjiu, Weng Weei
    Lv, Jian
    Wei, Chun
    JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (09)
  • [44] Facile preparation of PtPdPt/graphene nanocomposites with ultrahigh electrocatalytic performance for methanol oxidation
    Xie, Wenfu
    Zhang, Feifei
    Wang, Zonghua
    Yang, Min
    Xia, Jianfei
    Gui, Rijun
    Xia, Yanzhi
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2016, 761 : 55 - 61
  • [45] Flexible Poly(vinyl chloride) Nanocomposites Reinforced with Hyperbranched Polyglycerol-Functionalized Graphene Oxide for Enhanced Gas Barrier Performance
    Lee, Kyu Won
    Chung, Jae Woo
    Kwak, Seung-Yeop
    ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (38) : 33149 - 33158
  • [46] Poly(lactic acid)/p-phenylenediamine functionalized graphene oxidized nanocomposites: Preparation, rheological behavior and biodegradability
    Yang, Li
    Zhen, Weijun
    EUROPEAN POLYMER JOURNAL, 2019, 121
  • [47] In situ preparation of reduced graphene oxide/DOPO-based phosphonamidate hybrids towards high-performance epoxy nanocomposites
    Guo, Wenwen
    Yu, Bin
    Yuan, Yao
    Song, Lei
    Hu, Yuan
    COMPOSITES PART B-ENGINEERING, 2017, 123 : 154 - 164
  • [48] Characterization and Performance of Dodecyl Amine Functionalized Graphene Oxide and Dodecyl Amine Functionalized Graphene/High-Density Polyethylene Nanocomposites: A Comparative Study
    Ren, Peng-Gang
    Wang, Hao
    Huang, Hua-Dong
    Yan, Ding-Xiang
    Li, Zhong-Ming
    JOURNAL OF APPLIED POLYMER SCIENCE, 2014, 131 (02)
  • [49] Functionalized graphene nanoplatelets/poly(ethylene oxide) nanocomposites: Correlation between crystallization behavior and mechanical performance
    Gomari, Sepideh
    Ghasemi, Ismaeil
    Esfandeh, Masoud
    FIBERS AND POLYMERS, 2017, 18 (11) : 2153 - 2160
  • [50] Facile preparation of poly(ε-caprolactone)/Fe3O4@graphene oxide superparamagnetic nanocomposites
    Wang, Guangshuo
    Yang, Shu
    Wei, Zhiyong
    Dong, Xufeng
    Wang, Hong
    Qi, Min
    POLYMER BULLETIN, 2013, 70 (08) : 2359 - 2371
12345