3D Inorganic Cuprous Iodide Open-Framework Templated by In Situ N-Methylated 2,4,6-Tri(4-pyridyI)-1,3,5-triazine

被引：45
|
作者：
Sun, Ai-Huan [1 ]
Han, Song-De [1 ]
Pan, Jie [1 ]
Li, Jin-Hua [1 ]
Wang, Guo-Ming [1 ]
Wang, Zong-Hua [1 ]
机构：
[1] Qingdao Univ, Coll Chem & Chem Engn, Collaborat Innovat Ctr Marine Biomass Fiber Mat &, Qingdao 266071, Shandong, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2017年 / 17卷 / 07期
关键词：
METAL-ORGANIC FRAMEWORKS; PHASE-TRANSITION; LIGHT EMITTERS; HYBRID; HALIDE; CRYSTAL; TEMPERATURE; TOPOLOGY; IODOCUPRATES(I); COMPLEXES;
D O I：
10.1021/acs.cgd.7b00296
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel 3D inorganic cuprous iodide framework templated by in situ N-methylated 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) was solvothermally prepared and structurally characterized. The title compound bearing chiral cuprous iodide chains as building units is the first 3D extended framework with the TPT-derivatives as template. The UV-vis diffuse-reflectance measurement reveals that 1 possesses semiconductor behavior with band gaps of 1.35 eV. The photoluminescent property of 1 has also been studied.
引用
收藏
页码：3588 / 3591
页数：4
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