Comparison of the performance and durability of PEM fuel cells with different Pt-activated microporous layers

被引：16

作者：

Ivanova, Nataliya A. ^{[1
]}

Spasov, Dmitry D. ^{[1
,2
]}

Zasypkina, Adelina A. ^{[1
]}

Alekseeva, Olga K. ^{[1
]}

Kukueva, Elena, V ^{[1
]}

Vorobyeva, Ekaterina A. ^{[1
,3
]}

Kudinova, Ekaterina S. ^{[1
]}

Chumakov, Ratibor G. ^{[1
]}

Millet, Pierre ^{[4
]}

Grigoriev, Sergey A. ^{[1
,2
,5
]}

机构：

[1] Kurchatov Inst, Natl Res Ctr, 1 Akad Kurchatova Sq, Moscow 123182, Russia

[2] Natl Res Univ, Moscow Power Engn Inst, 14 Krasnokazarmennaya St, Moscow 111250, Russia

[3] Lomonosou Moscow State Univ, Skobeltsyn Inst Nucl Phys, 1 2 Leninskie Gory, Moscow 119991, Russia

[4] Univ Paris Saclay, Inst Chim Mol & Mat Orsay, UMR 8182, F-91405 Orsay, France

[5] North West Univ, Fac Engn, HySA Infrastruct Ctr Competence, ZA-2531 Potchefstroom, South Africa

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2021年 / 46卷 / 34期

基金：

俄罗斯基础研究基金会;

关键词：

PEM fuel cell; Platinum-activated microporous layer; Catalytic layer; Durability; Magnetron sputtering; GAS-DIFFUSION LAYER; REDUCED GRAPHENE OXIDE; ULTRA-LOW; LIQUID WATER; PLATINUM; ELECTROCATALYSTS; CATALYST; DEGRADATION; NANOPARTICLES; REDUCTION;

D O I：

10.1016/j.ijhydene.2020.08.234

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report on a comparative study of the performance level of H-2/O-2 PEM fuel cells in which the catalytic layers containing Pt nanoparticles were deposited on the microporous layer side of gas diffusion electrodes, using three different deposition techniques: (i) by magnetron sputtering, (ii) by impregnation followed by chemical reduction (using either ethylene glycol or hydrogen or sodium borohydride as reducing agent), and (iii) by spraying a catalytic ink (containing either Pt/C or bulk Pt particles). The microstructure and chemical composition of the different catalytic layers has been determined by SEM, TEM, XRD and XPS analysis. Their electrochemical surface areas have been determined by cyclic voltammetry. The i-V curves have been measured and compared. A durability stress test based on cycles of potential was used to assess the degradation rate of the different catalytic layers and to rank performance. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：18093 / 18106

页数：14

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