High-pressure structural phase transition and metallization in Ga2S3 under non-hydrostatic and hydrostatic conditions up to 36.4 GPa

被引：23

作者：

Yang, Linfei ^{[1
]}

Jiang, Jianjun ^{[2
]}

Dai, Lidong ^{[2
]}

Hu, Haiying ^{[2
]}

Hong, Meiling ^{[1
,3
]}

Zhang, Xinyu ^{[1
,3
]}

Li, Heping ^{[1
]}

Liu, Pengfei ^{[4
]}

机构：

[1] Chinese Acad Sci, Key Lab High Temp & High Pressure Study Earth Int, Inst Geochem, Guiyang 550081, Guizhou, Peoples R China

[2] Linyi Univ, Coll Resources & Environm Sci, Shandong Prov Key Lab Water & Soil Conservat & En, Linyi 276000, Shandong, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[4] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2021年 / 9卷 / 08期

基金：

中国科学院西部之光基金;

关键词：

TOPOLOGICAL INSULATORS; SB2TE3; BI2SE3; BI2TE3;

D O I：

10.1039/d0tc06004f

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The vibrational, electrical and structural properties of gallium sulfide (Ga2S3) were explored by Raman spectroscopy, electrical conductivity measurements, high-resolution transmission electron microscopy and first-principles theoretical calculations under different pressure environments up to 36.4 GPa. Upon compression, Ga2S3 underwent a first-order structural phase transition accompanied by a semiconductor-to-metal transformation at 17.2 GPa under non-hydrostatic conditions, whereas, the transition occurred at a much lower pressure of 11.3 GPa under hydrostatic conditions because of the influence of the pressure medium. Upon decompression, two possible new high-pressure polymorphs were observed at 8.0 and 3.0 GPa under non-hydrostatic conditions, and similar transition points were obtained under hydrostatic conditions. The structural and electrical transport evolution for Ga2S3 upon compression and decompression can help us to deeply understand the high-pressure behaviors of other similar A(2)B(3)-type structural compounds.

引用

页码：2912 / 2918

页数：7

共 38 条

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