High-resolution NMR correlation spectra of disordered solids

被引：105
作者：
Sakellariou, D
Brown, SP
Lesage, A
Hediger, S
Bardet, M
Meriles, CA
Pines, A
Emsley, L [1 ]
机构：
[1] Ecole Normale Super Lyon, Chim Lab, UMR 5532 CNRS ENS, F-69364 Lyon, France
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] CEA Grenoble, Serv Chim Inorgan & Biol, Grenoble, France
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 14期
关键词：
D O I：
10.1021/ja0292389
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We show how high-resolution NMR spectra can be obtained for solids for which the spectra are normally broadened due to structural disorder. The method relies on correlations in the chemical shifts between pairs of coupled spins. It is found experimentally that there are strong correlations in the chemical shifts between neighboring spins in both phosphorus-31 and carbon-13 spectra. These correlations can be exploited not only to provide resolution in two-dimensional spectra, but also to yield "chains" of correlated chemical shifts, constituting a valuable new source of structural information for disordered materials.
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页码：4376 / 4380
页数：5
相关论文
共 47 条
[1]   NUCLEAR MAGNETIC RESONANCE SPECTRA FROM A CRYSTAL ROTATED AT HIGH SPEED [J].
ANDREW, ER ;
BRADBURY, A ;
EADES, RG .
NATURE, 1958, 182 (4650) :1659-1659
[2]   High-resolution NMR in inhomogeneous fields [J].
Balbach, JJ ;
Conradi, MS ;
Cistola, DP ;
Tang, CG ;
Garbow, JR ;
Hutton, WC .
CHEMICAL PHYSICS LETTERS, 1997, 277 (04) :367-374
[3]  
BARDET M, 1986, HOLZFORSCHUNG, V40, P17
[4]   AN NMR TECHNIQUE FOR TRACING OUT THE CARBON SKELETON OF AN ORGANIC-MOLECULE [J].
BAX, A ;
FREEMAN, R ;
FRENKIEL, TA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (08) :2102-2104
[5]   THE DETECTION OF CONNECTIVITIES OF RARE SPIN-1/2 NUCLEI IN THE SOLID-STATE USING NATURAL ABUNDANCE SAMPLES - C-13 AND SI-29 INADEQUATE AND COSY TYPE EXPERIMENTS [J].
BENN, R ;
GRONDEY, H ;
BREVARD, C ;
PAGELOT, A .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (02) :102-103
[6]   HETERONUCLEAR DECOUPLING IN ROTATING SOLIDS [J].
BENNETT, AE ;
RIENSTRA, CM ;
AUGER, M ;
LAKSHMI, KV ;
GRIFFIN, RG .
JOURNAL OF CHEMICAL PHYSICS, 1995, 103 (16) :6951-6958
[7]   INHOMOGENEOUS BROADENING OF 2-DIMENSIONAL NMR LINESHAPES [J].
BROWN, SP ;
WIMPERIS, S .
CHEMICAL PHYSICS LETTERS, 1995, 237 (5-6) :509-515
[8]   The direct detection of a hydrogen bond in the solid state by NMR through the observation of a hydrogen-bond mediated 15N-15N J coupling [J].
Brown, SP ;
Pérez-Torralba, M ;
Sanz, D ;
Claramunt, RM ;
Emsley, L .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (07) :1152-1153
[9]  
EMSLEY L, 1999, P INT SCH PHYS E FER
[10]  
Ernst R. R., 1987, PRINCIPLES NUCL MAGN
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