Influence of VI/II ratios on the growth of ZnO thin films on sapphire substrates by low temperature MOCVD

被引:11
作者
Kong, Bo Hyun [1 ]
Kim, Dong Chan [1 ]
Mohanta, Sanjay Kumar [1 ]
Cho, Hyung Koun [1 ]
机构
[1] Sungkyunkwan Univ, Sch Adv Mat Sci & Engn, Suwon 440746, Gyeonggi Do, South Korea
基金
新加坡国家研究基金会;
关键词
Zinc oxide; MOCVD; Thin films; Photoluminescence; X-ray diffraction;
D O I
10.1016/j.tsf.2009.10.124
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We investigated the structural, electrical, and optical properties of ZnO thin films grown at different VI/II ratios on sapphire substrates by metalorganic chemical vapor deposition Transmission electron microscopy and X-ray diffraction revealed the epitaxial nature with a reduced dislocation density of the ZnO films grown at increased VI/II ratios The carrier concentration of the films increased to 4 9 x 10(18) cm(-3) and their resistivity decreased to 1 4 x 10(-1)Omega cm at a VI/II ratio of 513 4 mu mol/min The ZnO films also showed good optical transmittance (>80%) in the visible and near-infrared wavelength regions. The room temperature PL revealed a strong band-edge emission with a weak deep level emission, suggesting the good crystalline quality of the ZnO films on the sapphire substrates Furthermore, the intensity ratio of the band-edge emission to the deep-level emission (I-UV/I-Vis) increased with increasing VI/II ratio (C) 2009 Elsevier B V All rights reserved
引用
收藏
页码:2975 / 2979
页数:5
相关论文
共 17 条
[1]   Defect reduction by epitaxial lateral overgrowth of nanorods in ZnO/(0001) sapphire films [J].
Cherns, D. ;
Sun, Y. .
APPLIED PHYSICS LETTERS, 2008, 92 (05)
[2]   Properties of ZnO films grown on (0001) sapphire substrate using H2O and N2O as O precursors by atmospheric pressure MOCVD [J].
Dai, JN ;
Su, HB ;
Wang, L ;
Pu, Y ;
Fang, WQ ;
Jiang, FY .
JOURNAL OF CRYSTAL GROWTH, 2006, 290 (02) :426-430
[3]  
Gaul DA, 2000, ADV MATER, V12, P935, DOI 10.1002/1521-4095(200006)12:13<935::AID-ADMA935>3.0.CO
[4]  
2-J
[5]   Origin of green luminescence in ZnO thin film grown by molecular-beam epitaxy [J].
Heo, YW ;
Norton, DP ;
Pearton, SJ .
JOURNAL OF APPLIED PHYSICS, 2005, 98 (07)
[6]   Room-temperature ultraviolet nanowire nanolasers [J].
Huang, MH ;
Mao, S ;
Feick, H ;
Yan, HQ ;
Wu, YY ;
Kind, H ;
Weber, E ;
Russo, R ;
Yang, PD .
SCIENCE, 2001, 292 (5523) :1897-1899
[7]   Initial growth behavior and resulting microstructural properties of heteroepitaxial ZnO thin films on sapphire (0001) substrates [J].
Liu, C. ;
Chang, S. H. ;
Noh, T. W. ;
Abouzaid, M. ;
Ruterana, P. ;
Lee, H. H. ;
Kim, D. -W. ;
Chung, J. -S. .
APPLIED PHYSICS LETTERS, 2007, 90 (01)
[8]   The roles of structural imperfections in InGaN-Based blue light-emitting diodes and laser diodes [J].
Nakamura, S .
SCIENCE, 1998, 281 (5379) :956-961
[9]   A comprehensive review of ZnO materials and devices -: art. no. 041301 [J].
Ozgür, U ;
Alivov, YI ;
Liu, C ;
Teke, A ;
Reshchikov, MA ;
Dogan, S ;
Avrutin, V ;
Cho, SJ ;
Morkoç, H .
JOURNAL OF APPLIED PHYSICS, 2005, 98 (04) :1-103
[10]   Acoustic and optical phonon assisted formation of biexcitons [J].
Pan, Ching-Ju ;
Lin, Kuo-Feng ;
Hsieh, Wen-Feng .
APPLIED PHYSICS LETTERS, 2007, 91 (11)