A study on the phase diagram of the LaCl3-CdC2-(9.7%)HCl-H2O system at 298K and its compounds characterized

被引：0

作者：

Li, L

Wang, H ^{[1
]}

Xia, SP

Hu, MC

Gao, SY

机构：

[1] NW Univ Xian, Dept Chem, Shaanxi Prov Key Lab Phys & Inorgan Chem, Xian 710069, Peoples R China

[2] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Peoples R China

[3] Lanzhou Univ, Inst Chem Engn, Lanzhou 730000, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 19卷 / 02期

关键词：

quaternary system; phase equilibrium; cadmium chloride; lanthanum chloride; 8CdCl(2) center dot LaCl3 center dot 16H(2)O (8 : 1 type) 4CdCl(2) center dot LaCl3 center dot 12H(2)O (4 : 1 type);

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The equilibrium solubility of the LaCl3-CdCl2-(9.7%) HCl-H2O quaternary system at 298K was determined and the phase diagram was constructed. The results show that the system is complicated with four equilibrium solid-phases CdCl2 (.) H2O, 8CdCl(2) (.) LaCl3 (.) 16H(2)O(8:1 type), 4CdCl(2) (.) LaCl3 (.) 12H(2)O(4:1 type) and LaCl3 (.) 7H(2)O, respectively. The two new compounds 8CdCl(2) (.) LaCl3 (.) 16H(2)O(8:1 type) and 4CdCl(2) (.) LaCl3 (.) 12H(2)O(4:1 type) are congruently soluble in - 9. 7% HCl-H2O medium and have not yet been reported in literatures. Both compounds have been prepared from the system and have been characterized by XRD, TG-DTG and DSC.

引用

页码：201 / 205

页数：5