Synthesis and molecular structure of 1,3-di-tert-butyl-2,4-bis(cyclodipentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(η5-C5H4)2(PNtBu)2]

被引：30
作者：
Balakrishna, Maravanji S. [1 ]
Mague, Joel T.
机构：
[1] Indian Inst Technol, Dept Chem, Phosphorus Lab, Bombay 400076, Maharashtra, India
[2] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA
来源：
ORGANOMETALLICS | 2007年 / 26卷 / 18期
关键词：
D O I：
10.1021/om700423h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the dichlorocyclodiphosphazane (also called dichlorodiazadiphosphetidine), [ClP(mu-(NBu)-Bu-t)](2), with in situ generated ferrocene dilithiate in a 1:1 molar ratio affords the first metallocene derivative of a diazadiphosphetidine, 1,3-di-tert-butyl-2,4-bis(cyclopentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(eta(5)-C5H4)(2)((PNBu)-Bu-t)(2)], in good yield.
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页码：4677 / 4679
页数：3
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