Synthesis and molecular structure of 1,3-di-tert-butyl-2,4-bis(cyclodipentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(η5-C5H4)2(PNtBu)2]

被引：30

作者：

Balakrishna, Maravanji S. ^{[1
]}

Mague, Joel T.

机构：

[1] Indian Inst Technol, Dept Chem, Phosphorus Lab, Bombay 400076, Maharashtra, India

[2] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 18期

关键词：

D O I：

10.1021/om700423h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the dichlorocyclodiphosphazane (also called dichlorodiazadiphosphetidine), [ClP(mu-(NBu)-Bu-t)](2), with in situ generated ferrocene dilithiate in a 1:1 molar ratio affords the first metallocene derivative of a diazadiphosphetidine, 1,3-di-tert-butyl-2,4-bis(cyclopentadienyl)iron(II) 1,3,2,4-diazadiphosphetidine, [Fe(eta(5)-C5H4)(2)((PNBu)-Bu-t)(2)], in good yield.

引用

页码：4677 / 4679

页数：3

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