Microwave-assisted synthesis of LiCoO2 and LiCo1-xGaxO2: Structural features, magnetism and electrochemical characterization

被引：8

作者：

Gonzalo, E. C. ^{[3
]}

Moran, E. ^{[1
]}

Parada, C. ^{[1
]}

Ehrenberg, H. ^{[2
]}

机构：

[1] Univ Complutense, Fac CC Quim, Dept Quim Inorgan, E-28040 Madrid, Spain

[2] Leibnitz Inst Festkorper & Werkstofforsch Dresden, D-01069 Dresden, Germany

[3] Univ San Pablo CEU, Fac Farm, Dept Quim, Madrid 28023, Spain

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2010年 / 121卷 / 03期

关键词：

Microwave synthesis; Nanosized materials; Lithium cobalt oxide; Lithium-ion batteries; MG-DOPED LICOO2; CATHODE MATERIALS; LITHIUM; LI; OXIDES; PERFORMANCE; AL; CO; DEINTERCALATION; INTERCALATION;

D O I：

10.1016/j.matchemphys.2010.02.011

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Nanocrystalline (between 30 and 40 nm) LiCoO2 and LiCo1-xGaxO2 (0 <= x <= 0.15) powders have been prepared by using a standard microwave furnace. Depending on the power and irradiation time, nanosized LT-LiCo1-xGa5O2 (cubic) or HT-LiCo1-xGaxO2 (hexagonal) (0 <= x <= 0.15) materials have been obtained and studied by means of X-ray diffraction, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Electrochemical characterization and magnetic behaviour of the electrochemical active polymorphs (HT-phases) have also been investigated. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：484 / 488

页数：5

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