Tris(pentafluorophenyl) borane as an electrolyte additive for Li-O2 batteries

被引：5
作者：
Kartal, M. [1 ]
Uysal, M. [1 ]
Alp, A. [1 ]
Akbulut, H. [1 ]
机构：
[1] Sakarya Univ, Fac Engn, Dept Met & Mat Engn, Esentepe Campus, TR-54187 Sakarya, Turkey
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2016年 / 41卷 / 18期
关键词：
Li-O-2; batteries; Electrolyte additive; TEGDME; TPFPB; LI-AIR; CATHODE CATALYSTS; GRAPHENE OXIDE; LITHIUM-ION; PERFORMANCE; REDUCTION; STABILITY; LI2O2;
D O I：
10.1016/j.ijhydene.2016.02.092
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
TPFPB was used as an additive in a rechargeable Li-O-2. cell utilizing an electrolyte composed of a solution 1 M LiPF6 in tetraethylene glycol dimethyl ether (TEGDME) to investigate the effects on capacity and cycling performances. Capacity limitation was also applied to the cells and results were compared with full charging and discharging condition. Galvanostatic charge/discharge (GC) measurements were performed in the assembled Li-O-2 cells using assembled cells, designed with different electrolytes. Cell discharge capacities were cyclically tested by a battery tester at a constant current in voltage range between 2.15 V-4.25 V. Discharge products of the electrolytes characterized by SEM and XRD techniques. The electrochemical results showed increasing discharge capacity and cycleability of the assembled cells produced with TPFPB as compared to TPFPB free electrolytes. Copyright (C) 2016, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：7600 / 7608
页数：9
相关论文
共 32 条
[1]   A critical review on lithium-air battery electrolytes [J].
Balaish, Moran ;
Kraytsberg, Alexander ;
Ein-Eli, Yair .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (07) :2801-2822
[2]   Free-standing flexible graphene oxide paper electrode for rechargeable Li-O2 batteries [J].
Cetinkaya, Tugrul ;
Ozcan, Seyma ;
Uysal, Mehmet ;
Guler, Mehmet O. ;
Akbulut, Hatem .
JOURNAL OF POWER SOURCES, 2014, 267 :140-147
[3]   Tris(pentafluorophenyl) borane as an electrolyte additive for LiFePO4 battery [J].
Chang, Chia-Chin ;
Chen, Te-Kang .
JOURNAL OF POWER SOURCES, 2009, 193 (02) :834-840
[4]   Tris(pentafluorophenyl) borane-containing electrolytes for electrochemical reversibility of lithium peroxide-based electrodes in lithium-oxygen batteries [J].
Choi, Nam-Soon ;
Jeong, Goojin ;
Koo, Bonjae ;
Lee, Yong-Won ;
Lee, Kyu Tae .
JOURNAL OF POWER SOURCES, 2013, 225 :95-100
[5]   Effect of lithium ions on oxygen reduction in ionic liquid-based electrolytes [J].
De Giorgio, Francesca ;
Soavi, Francesca ;
Mastragostino, Marina .
ELECTROCHEMISTRY COMMUNICATIONS, 2011, 13 (10) :1090-1093
[6]   Oxygen reduction reaction of different electrodes in dimethyl sulfoxide solvent for Li-air batteries [J].
Duan, Donghong ;
You, Xiu ;
Ren, Wenjun ;
Wei, Huikai ;
Liu, Huihong ;
Liu, Shibin .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (34) :10847-10855
[7]  
FREUNBERGER SA, 2011, CHEM INT ED, V50, P8609, DOI DOI 10.1002/ANIE.201102357
[8]  
GAO Y, 2012, HYDROGEN ENERGY, V37, P12725, DOI DOI 10.1016/J.IJHYDENE.2012.03.127
[9]   Lithium - Air Battery: Promise and Challenges [J].
Girishkumar, G. ;
McCloskey, B. ;
Luntz, A. C. ;
Swanson, S. ;
Wilcke, W. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (14) :2193-2203
[10]   Tris(pentafluorophenyl) borane as an electrolyte additive for high performance silicon thin film electrodes in lithium ion batteries [J].
Han, Gi-Beom ;
Lee, Je-Nam ;
Choi, Jang Wook ;
Park, Jung-Ki .
ELECTROCHIMICA ACTA, 2011, 56 (24) :8997-9003
1234