Molecular imprinting in chemical sensing - Detection of aromatic and halogenated hydrocarbons as well as polar solvent vapors

被引:79
作者
Dickert, FL [1 ]
Forth, P [1 ]
Lieberzeit, P [1 ]
Tortschanoff, M [1 ]
机构
[1] Univ Vienna, Inst Analyt Chem, A-1090 Vienna, Austria
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1998年 / 360卷 / 7-8期
关键词
Polymer; Hydrocarbon; Resonant Frequency; Oscillation Frequency; Solvent Vapor;
D O I
10.1007/s002160050801
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The technique of molecular imprinting - a novel tool of sensor material synthesis - can be successfully combined with mass-sensitive transducers. Imprinted polymers are prepared in presence of inert analytes acting as molecular templates. The remaining imprint allows the molecular recognition of an analyte due to host-guest-interactions. The sensor properties of devices coated with imprint polymers can be tuned to the analyte by variation of the polymerization solvent and the amount of cross-linker added. A further sensitivity enhancement can be achieved by rising the resonant frequencies of QMBs and SAW resonators, since the signal to noise-ratio increases in an approximately linear manner with the oscillation frequency.
引用
收藏
页码:759 / 762
页数:4
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