Peculiarities in electrical and optical properties of Cu2Zn1-x Mn x SnS4 films obtained by spray pyrolysis

被引：19
作者：
Orletskii, I. G. [1 ]
Mar'yanchuk, P. D. [1 ]
Solovan, M. N. [1 ]
Maistruk, E. V. [1 ]
Kozyarskii, D. P. [1 ]
机构：
[1] Yuriy Fedkovych Chernivtsi Natl Univ, UA-58012 Chernovtsy, Ukraine
来源：
TECHNICAL PHYSICS LETTERS | 2016年 / 42卷 / 03期
关键词：
Technical Physic Letter; Spray Pyrolysis; Manganese Content; Aqueous Salt Solution; Specific Electric Conductivity;
D O I：
10.1134/S1063785016030263
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Thin films of Cu2Zn1-x Mn (x) SnS4 (0 a parts per thousand currency sign x a parts per thousand currency sign 1) solid solutions have been obtained for the first time by the spray pyrolysis of aqueous salt solutions (copper, zinc, manganese, and tin chlorides and thiourea) at a temperature of T (S) = 563 K. The films possess specific electric conductivities within sigma a parts per thousand 35-422 Omega(-1) cm(-1) and optical bandgap width E (g) (op) that increases with the manganese content from 1.54 eV (x = 0) to 2.25 eV (x = 1). Electrical and optical properties of the obtained films have been studied and analyzed based on a model of polycrystalline materials with grain boundaries. The energy barriers Eb between grains have been determined. The dependence of the bandgap of Cu2Zn1-x Mn (x) SnS4 (0 a parts per thousand currency sign x a parts per thousand currency sign 1) solid solutions on the composition has been established using the results of measurements of the optical transmission and absorption coefficients.
引用
收藏
页码：291 / 294
页数：4
相关论文
共 50 条
  • [31] Structure and optical properties of Zn1-xFexO thin films prepared by ultrasonic spray pyrolysis
    Alver, U.
    Kilinc, T.
    Bacaksiz, E.
    Nezir, S.
    [J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2007, 138 (01): : 74 - 77
  • [32] X-ray diffraction and compositional studies of AgInS2 thin films obtained by spray pyrolysis
    M. Calixto-Rodriguez
    A. Tiburcio-Silver
    A. Sanchez-Juarez
    M. E. Calixto
    [J]. Journal of Materials Science, 2008, 43 : 6848 - 6852
  • [33] Structure of Ag-Containing Cu2ZnSnS4 Thin Films, Obtained by Spray Pyrolysis
    Zgliui A.A.
    Tivanov M.S.
    Curmei N.N.
    Dermenji L.V.
    Bruc L.I.
    Serban D.A.
    [J]. Applied Solar Energy (English translation of Geliotekhnika), 2023, 59 (03): : 189 - 200
  • [34] Structural and transport properties of Cu2CoSnS4 films prepared by spray pyrolysis
    El Khouja, Outman
    Assahsahi, Ilhame
    Nouneh, Khalid
    Touhami, Mohamed Ebn
    Secu, Mihail
    Talbi, Abdelali
    Khaaissa, Yassine
    Matei, Elena
    Stancu, Viorica
    Galatanu, Andrei
    Galca, Aurelian Catalin
    [J]. CERAMICS INTERNATIONAL, 2022, 48 (21) : 32418 - 32426
  • [35] Absence of Mn emission in MnxZn(1-x)S thin films grown by spray pyrolysis technique
    Krishna, Ganesha V. S.
    Mahesha, M. G.
    [J]. JOURNAL OF LUMINESCENCE, 2021, 230 (230)
  • [36] Secondary phases in Cu2ZnSnS4 films obtained by spray pyrolysis at different substrate temperatures and Cu contents
    Babichuk, I. S.
    Golovynskyi, S.
    Brus, V. V.
    Babichuk, I. V.
    Datsenko, O.
    Li, Ji
    Xu, Guiwen
    Golovynska, I.
    Hreshchuk, O. M.
    Orletskyi, I. G.
    Qu, Junle
    Yukhymchuk, V. O.
    Maryanchuk, P. D.
    [J]. MATERIALS LETTERS, 2018, 216 : 173 - 175
  • [37] Low-temperature spray-pyrolysis of FeS2 films and their electrical and optical properties
    I. G. Orletskii
    P. D. Mar’yanchuk
    E. V. Maistruk
    M. N. Solovan
    V. V. Brus
    [J]. Physics of the Solid State, 2016, 58 : 37 - 41
  • [38] Optical and electrical properties of Sn2S3 thin films grown by spray pyrolysis
    Khadraoui, M.
    Benramdane, N.
    Mathieu, C.
    Bouzidi, A.
    Miloua, R.
    Kebbab, Z.
    Sahraoui, K.
    Desfeux, R.
    [J]. SOLID STATE COMMUNICATIONS, 2010, 150 (5-6) : 297 - 300
  • [39] The morphological, optical and electrical properties of SnO2:F thin films prepared by spray pyrolysis
    Zhi, Xiao
    Zhao, Gaoyang
    Zhu, Tao
    Li, Ying
    [J]. SURFACE AND INTERFACE ANALYSIS, 2008, 40 (02) : 67 - 70
  • [40] Optical and Electrical Properties of Large Area SnO2: F Thin Films by Spray Pyrolysis
    Zhao, Gaoyang
    Ren, Yang
    Gao, Yun
    Shen, Jie
    [J]. ECO-MATERIALS PROCESSING AND DESIGN XI, 2010, 658 : 81 - 84
12345