Upgrading biomass-derived furans via acid-catalysis/hydrogenation: the remarkable difference between water and methanol as the solvent

被引：92

作者：

Hu, Xun ^{[1
]}

Westerhof, Roel J. M. ^{[1
]}

Wu, Liping ^{[1
]}

Dong, Dehua ^{[1
]}

Li, Chun-Zhu ^{[1
]}

机构：

[1] Curtin Univ Technol, Fuels & Energy Technol Inst, Perth, WA 6845, Australia

来源：

GREEN CHEMISTRY | 2015年 / 17卷 / 01期

关键词：

CATALYZED CONVERSION; FURFURYL ALCOHOL; PLATFORM CHEMICALS; ETHYL LEVULINATE; DEHYDRATION; EFFICIENT; XYLOSE; GLUCOSE; SUGARS; PART;

D O I：

10.1039/c4gc01826e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In methanol 5-hydroxymethylfurfural (HMF) and furfuryl alcohol (FA) can be selectively converted into methyl levulinate via acid-catalysis, whereas in water polymerization dominates. The hydrogenation of HMF, furan and furfural with the exception of FA is much more selective in methanol than in water.

引用

页码：219 / 224

页数：6

共 47 条

[1] Furfural production from xylose plus glucose feedings and simultaneous N2-stripping [J].

Agirrezabal-Telleria, I. ;

Requies, J. ;

Gueemez, M. B. ;

Arias, P. L. .

GREEN CHEMISTRY, 2012, 14 (11) :3132-3140

[2]

Alonso DM, 2013, ENERG ENVIRON SCI, V6, P76, DOI [10.1039/C2EE23617F, 10.1039/c2ee23617f]

[3] Catalytic conversion of biomass to biofuels [J].

Alonso, David Martin ;

Bond, Jesse Q. ;

Dumesic, James A. .

GREEN CHEMISTRY, 2010, 12 (09) :1493-1513

[4]

[Anonymous], 2010, ANGEW CHEM, DOI DOI 10.1002/ANGE.201000655

[5] Simple Chemical Transformation of Lignocellulosic Biomass into Furans for Fuels and Chemicals [J].

Binder, Joseph B. ;

Raines, Ronald T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (05) :1979-1985

[6] Integrated Catalytic Process to Directly Convert Furfural to Levulinate Ester with High Selectivity [J].

Chen, Bingfeng ;

Li, Fengbo ;

Huang, Zhijun ;

Lu, Tao ;

Yuan, Yin ;

Yuan, Guoqing .

CHEMSUSCHEM, 2014, 7 (01) :202-209

[7] Production of targeted aromatics by using Diels-Alder classes of reactions with furans and olefins over ZSM-5 [J].

Cheng, Yu-Ting ;

Huber, George W. .

GREEN CHEMISTRY, 2012, 14 (11) :3114-3125

[8] A two-step approach for the catalytic conversion of glucose to 2,5-dimethylfuran in ionic liquids [J].

Chidambaram, Mandan ;

Bell, Alexis T. .

GREEN CHEMISTRY, 2010, 12 (07) :1253-1262

[9] Conversion of biomass platform molecules into fuel additives and liquid hydrocarbon fuels [J].

Climent, Maria J. ;

Corma, Avelino ;

Iborra, Sara .

GREEN CHEMISTRY, 2014, 16 (02) :516-547

[10] Acidic cesium salts of 12-tungstophosphoric acid as catalysts for the dehydration of xylose into furfural [J].

Dias, Ana S. ;

Lima, Sergio ;

Pillinger, Martyn ;

Valente, Anabela A. .

CARBOHYDRATE RESEARCH, 2006, 341 (18) :2946-2953

← 1 2 3 4 5 →