Mn-55, (CO)-C-13 and Mn-55, P-31 coupling constants of organomanganese complexes: Comparison of NMR results from experiments in solution and in the solid state?

被引：0

作者：

Rentsch, D

Hany, R

vonPhilipsborn, W

机构：

[1] UNIV ZURICH,INST ORGAN CHEM,CH-8057 ZURICH,SWITZERLAND

[2] SWISS FED LABS MAT TESTING & RES EMPA,CH-8600 DUBENDORF,SWITZERLAND

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1997年 / 35卷 / 12期

关键词：

NMR; magic angle spinning; Mn-55; P-31; C-13; scalar and quadrupole coupling constants; organomanganese complexes;

D O I：

10.1002/(SICI)1097-458X(199712)35:12<832::AID-OMR185>3.0.CO;2-S

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Scalar spin-spin coupling constants of some organomanganese complexes, Mn(CO)(5-n)(R)L-n, were evaluated by lineshape analysis from C-13 and P-31 solution NMR spectra and from solid-state magic angle spinning spectra showing first-order splitting. Consistent results were obtained for favourable complexes, but each method has only limited applicability in the general case. The merits of both methods are discussed. (C) 1997 John Wiley & Sons, Ltd.

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页码：832 / 838

页数：7

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