New syntheses and crystal structures of bis(fluorophenyl) mercury, Hg(Rf)2 (Rf = C6F5, 2,3,4,6-F4C6H, 2,3,5,6-F4C6H, 2,4,6-F3C6H2, 2,6-F2C6H3)

被引：6

作者：

Naumann, D ^{[1
]}

Schulz, F ^{[1
]}

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 01期

关键词：

mercury; fluorophenyl compounds; crystal structures;

D O I：

10.1002/zaac.200400244

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(fluorophenyl) mercury compounds, Hg(R-f)(2) (R-f = C6F5, C6HF4, C6H2F3, C6H3F2), are prepared in good yields by the reactions of HgF2 with Me3SiRf. The crystal structures of Hg(2,3,4,6-F4C6H)(2) (monoclinic, P2(1)/n), Hg(2,3,5,6-F4C6H)(2) (monoclinic, C2/m), Hg(2,4,6-F3C6H2)(2) (monoclinic, P2(1)/c) and Hg(2,6-F2C6H3)(2) (triclinic, P (1) over bar) are described.

引用

页码：122 / 125

页数：4

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